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Transformation of Glucose to 5-Hydroxymethylfurfural Over Regenerated Cellulose Supported Nb2O5·nH2O in Aqueous Solution

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Abstract

Niobic acid (Nb2O5·nH2O) was immobilized on regenerated cellulose (Re-Cellulose) to afford a heterogeneous catalyst, termed Nb2O5·nH2O@Re-Cellulose, that was characterized by powder X-ray diffraction, microscopy (SEM and TEM) and spectroscopic (Raman and FTIR) techniques. The surface acidity of the catalyst was determined using FTIR spectroscopy employing pyridine as a molecular probe. The Nb2O5·nH2O@Re-Cellulose catalyst was investigated in the conversion of glucose into 5-hydroxymethylfurfural (HMF) in aqueous media. The catalyst can be reused several times without undergoing a significant loss in activity.

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Acknowledgements

This research is funded by NSFC (Grant No. 21503098).

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Authors and Affiliations

  1. School of Chemistry and Materials Science, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, 221116, People’s Republic of China

    Fangmin Huang, Tianying Jiang, Hongyu Dai, Xincheng Xu & Shili Jiang

  2. Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland

    Fangmin Huang, Lu Chen, Zhaofu Fei & Paul J. Dyson

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  1. Fangmin Huang
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  2. Tianying Jiang
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  3. Hongyu Dai
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  6. Lu Chen
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  7. Zhaofu Fei
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Correspondence to Fangmin Huang.

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Huang, F., Jiang, T., Dai, H. et al. Transformation of Glucose to 5-Hydroxymethylfurfural Over Regenerated Cellulose Supported Nb2O5·nH2O in Aqueous Solution. Catal Lett 150, 2599–2606 (2020). https://doi.org/10.1007/s10562-020-03160-9

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  • DOI: https://doi.org/10.1007/s10562-020-03160-9

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