Abstract
Rhodamine B (RhB) and tetracycline (TC) are the typical organic pollutants in wastewater. More and more attentions have been paid to the removal of them. In the present work, pure and various contents of Ce3+ doped Bi2MoO6 nanostructures were synthesized by a facile hydrothermal method. They were characterized by X-ray diffraction (XRD), UV–Vis diffuse reflectance spectra (UV–Vis DRS), Raman spectra, photoluminescence spectra, scanning electron microscopy (SEM), N2 adsorption–desorption tests and X-ray photoelectron spectra. XRD patterns show that the pure and Ce3+ doped Bi2MoO6 exhibit orthorhombic crystal structure and Ce3+ is successfully doped into Bi2MoO6 lattice. UV–Vis DRS results indicate that a narrower band gap was obtained after Ce3+ doped into Bi2MoO6. SEM images show that the Ce-doped Bi2MoO6 is 3D microspheres constructed by many nanosheets. The photocatalytic activities of the as-prepared samples were evaluated by the degradation of RhB and TC. The 0.5% Ce3+ doped Bi2MoO6 exhibits the best photocatalytic activity of 96.6% within 20 min for RhB removal and 78.2% within 90 min for TC removal, respectively. The improved photocatalytic activity can be ascribed to the low recombination and easy migration of photogenerated electron hole pairs derived from the better crystallinity, optimum optical absorption activity and morphology of microspheres after Ce3+ doping. In addition, it also had a good stability and reusability after ten times of recycling experiments.
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Li XY, Wang LP, Xu DB et al (2015) CrystEngComm 17:2421
Mousavi M, Habibi-Yangjeh A, Pouran SR (2018) J Mater Sci: Mater Electron 29:1719
Shekofteh M, Habibi-Yangjeh A, Abitorabi M et al (2018) Crit Rev Environ Sci Technol 48:806
Zhang XH (2017) Indian J Chem A 56:1028
Pirhashemi M, Habibi-Yangjeh A, Pouran SR (2018) J Ind Eng Chem 62:1
Habibi-Yangjeh A, Mousavi M (2018) Adv Powder Technol 29:1379
Asadzadeh-Khaneghah S, Habibi-Yangjeh A, Seifzadeh D (2018) J Taiwan Inst Chem Eng 87:98
Habibi-Yangjeh A, Mousavi M, Nakata K (2019) J Photochem Photobiol A Chem 368:120
Pirhashemi M, Habibi-Yangjeh A (2018) J Photochem Photobiol A Chem 363:31
Feizpoor S, Habibi-Yangjeh A (2018) J Colloid Interface Sci 524:325
Lin SJ, Du WT, Tong LG et al (2019) Chem Res Chin Univ 35:120
Patiphatpanya P, Ekthammathat N, Phuruangrat A et al (2018) Russ J Phys Chem A 92:2289
Hu JQ, He HC, Li L et al (2019) Chem Commun 55:4777
Kweku DW, Beryl AB, Masso Kody CS et al (2019) Catal Sci Technol 9:546
Basith MA, Yesmin N, Hossain R (2018) RSC Adv 8:29613
Ni ZL, Sun YJ, Zhang YX et al (2016) Appl Surf Sci 365:314
Zhang XH, Gai WZ (2017) J Mater Sci: Mater Electron 28:9777
Yu HB, Jiang LB, Wang H et al (2019) Small. https://doi.org/10.1002/smll.201901008
Zhang P, Yi YN, Yu CX et al (2018) J Mater Sci: Mater Electron 29:8617
Jia YL, Lin YH, Ma Y et al (2018) Mater Lett 234:83
Yang ZX, Shen M, Dai K et al (2018) Appl Surf Sci 430:505
Jia YL, Ma Y, Tang JZ et al (2018) Dalton Trans 47:5542
Xing YX, Gao XC, Ji GF et al (2019) Appl Surf Sci 465:369
Hu TP, Yang Y, Dai K et al (2018) Appl Surf Sci 456:473
Liu HJ, Du CW, Bai HK et al (2018) J Mater Sci 53:10743
Jaffari ZH, Lam SM, Sin JC et al (2019) Environ Sci Pollut Res 26:10204
Chen W, Wang YH, Shangguan WF (2019) Mater Lett 238:74
Zhang XH (2014) Catal Lett 144:1253
Xue SS, He HB, Fan QZ et al (2017) J Environ Sci 60:70
Jia H, Liu ZL, Liao LM et al (2018) J Phys Chem C 122:9606
Wang W, Ding MY, Lu CH et al (2014) Appl Catal B 144:379
Wang M, You MY, Guo PY et al (2017) J Alloy Compd 728:739
Chen P, Zhong Z, Jia H et al (2016) RSC Adv 6:7391
Zhang FJ, Sun R, Li RS et al (2018) J Sol Gel Sci Technol 86:640
Alemi AA, Kashfi R, Shabani B et al (2014) J Mol Catal A: Chem 392:290
Ri CN, Kim SG, Ju KS et al (2018) RSC Adv 8:5433
Li HD, Li WJ, Liu XT et al (2019) Appl Surf Sci 463:556
Sun YJ, Wang H, Xing Q et al (2019) Chin J Catal 40:647
Chang CJ, Huang KL, Chen JK et al (2015) J Taiwan Inst Chem Eng 56:82
Wang M, Zheng HY, Liu J et al (2015) Mater Sci Semicond Process 30:307
Li HH, Liu CY, Li KW et al (2008) J Mater Sci 43:7026
Zhou F, Shi R, Zhu YF (2011) J Mol Catal A: Chem 340:77
Zhang LW, Xu TG, Zhao X et al (2010) Appl Catal B Environ 98:138
Zhang XH, Zhao JG, Guo LJ (2014) J Alloy Compd 582:617
Jiang ZY, Liu YY, Jing T et al (2016) J Phys Chem C 120:2058
Rahmani M, Sedaghat T (2019) J Inorg Organomet Polym 29:220
Regmi C, Kshetri YK, Kim TH et al (2017) Appl Surf Sci 413:253
Shang YR, Cui YP, Shi RX et al (2019) Mat Sci Semicond Process 89:240
Acknowledgements
The author gratefully acknowledges the financial support of the Henan Provincial Department of Science and Technology Research Project (Nos. 162102210303, 182102311047) and the Key Program of Colleges and Universities in Henan Province (No. 18A150039).
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Zhang, X., Zhang, H., Jiang, H. et al. Hydrothermal Synthesis and Characterization of Ce3+ Doped Bi2MoO6 for Water Treatment. Catal Lett 150, 159–169 (2020). https://doi.org/10.1007/s10562-019-02924-2
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DOI: https://doi.org/10.1007/s10562-019-02924-2