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Kinetics of Allyl Alcohol Epoxidation with Hydrogen Peroxide Catalyzed by a TS-1/Al2O3

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Abstract

The kinetics of oxidation of allyl alcohol to glycidol in the presence of extruded titanium silicalite was investigated. Based on the experimental data obtained, a kinetic model of the process was developed and the activation energies of the target and side reactions, the rate constants and the adsorption equilibrium were determined. Testing of the process of allyl alcohol epoxidation was carried out and the adequacy of the proposed kinetic model was evaluated at the bench laboratory installation of continuous action.

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Acknowledgements

The work is executed at financial support of the Ministry of Education and Science of the Russian Federation (Agreement No. 14.577.21.0093 for a subvention, a unique identifier of applied research (Project) RFMEFI57714X0093).

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  1. Nizhny Novgorod State Technical University n.a. R.E.Alekseev, Minin Street, 24, Nizhny Novgorod, Russian Federation, 603950

    A. Sulimov, A. Ovcharova, A. Ovcharov & J. Sulimova

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  1. A. Sulimov
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Sulimov, A., Ovcharova, A., Ovcharov, A. et al. Kinetics of Allyl Alcohol Epoxidation with Hydrogen Peroxide Catalyzed by a TS-1/Al2O3. Catal Lett 149, 3076–3086 (2019). https://doi.org/10.1007/s10562-019-02877-6

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