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A Kinetic Model for the Epoxidation of Allyl Alcohol with Hydrogen Peroxide on Titanium Silicate TS-1

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Abstract

The kinetic regularities of the oxidation of allyl alcohol into glycidol in the presence of titanium silicate are studied at varied initial concentrations of the reagents, products, and temperature. The probable mechanism is used as the basis to develop a substantial kinetic model, which adequately describes the obtained experimental data.

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Authors and Affiliations

  1. Alekseev Nizhny Novgorod State Technical University, Nizhny Novgorod, 603950, Russia

    A. V. Sulimov, S. M. Danov & A. V. Ovcharova

  2. Moscow Technological University, Moscow, 119571, Russia

    V. R. Flid & L. G. Bruk

Authors
  1. A. V. Sulimov
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  2. S. M. Danov
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  3. A. V. Ovcharova
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  4. V. R. Flid
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  5. L. G. Bruk
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Corresponding author

Correspondence to A. V. Sulimov.

Additional information

Original Russian Text © A.V. Sulimov, S.M. Danov, A.V. Ovcharova, V.R. Flid, L.G. Bruk, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 6, pp. 688–694.

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Sulimov, A.V., Danov, S.M., Ovcharova, A.V. et al. A Kinetic Model for the Epoxidation of Allyl Alcohol with Hydrogen Peroxide on Titanium Silicate TS-1. Kinet Catal 58, 673–678 (2017). https://doi.org/10.1134/S0023158417060118

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  • DOI: https://doi.org/10.1134/S0023158417060118

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