Abstract
Enabling solar and/or visible light-driven photocatalysis is a crucial step to access innovative applications in environmental science and sustainable energy. Titanium dioxide is the most used photocatalyst because of its low cost and toxicity, however it is also limitedly active under visible light irradiation due to its wide band gap. Among its polymorphs, brookite holds promising optoelectronic properties for visible light photocatalysis, which have to the best of our knowledge been limitedly exploited. Here, a C,S,N-doped brookite-based TiO2 has been prepared via a rapid one-pot sol–gel synthesis. Besides substantially extending the visible light absorption via band gap narrowing, its photocatalytic activity has been enhanced further by optimising valence and conductive band position and by minimising electron–hole recombination. These materials showed a 100% boost in visible light absorption along with nearly 50-times enhanced photocatalytic activity per specific surface area than standard TiO2 Degussa-P25, giving the best performance among the brookite-based photo-catalytically active materials and resulting among the TiO2 top-performers under visible light.
Graphical Abstract
Similar content being viewed by others
References
Zhang Q, Huang Y, Xu LF, Cao JJ, Ho WK, Lee SC (2016) ACS Appl Mater Interfaces 8:4165
Faraldos M, Kropp R, Anderson MA, Sobolev K (2016) Catal Today 259:228
Banerjee S, Dionysiou DD, Pillai SC (2015) Appl Catal B 176:396
Ganesh VA, Raut HK, Nair AS, Ramakrishna S (2011) J Mater Chem 21:16304
Zhang W, Jia B, Wang Q, Dionysiou D (2015) J Nanopart Res 17:1
Romão J, Barata D, Ribeiro N, Habibovic P, Fernandes H, Mul G (2017) Environ Pollut 220:1199
Fujishima A, Honda K (1972) Nature 238:37
Acar C, Dincer I, Naterer GF (2016) Int J Energy Res 40:1449
Jafari T, Moharreri E, Amin AS, Miao R, Song W, Suib SL (2016) Molecules 21:900
Ampelli C, Centi G, Passalacqua R, Perathoner S (2016) Catal Today 259:246
Guo Q, Zhou C, Ma Z, Ren Z, Fan H, Yang X (2016) Chem Soc Rev 45:3701
Landmann M, Rauls E, Schmidt WG (2012) J Phys Condens Matter 24:195503
Luttrell T, Halpegamage S, Tao J, Kramer A, Sutter E, Batzill M (2014) Sci Rep 4:4043
Kim W, Tachikawa T, Moon G-h, Majima T, Choi W (2014) Angew Chem Int Ed 53:14036
Di Paola A, Bellardita M, Palmisano L (2013) Catalysts 3:36
Banerjee S, Gopal J, Muraleedharan P, Tyagi K, Raj B (2006) Curr Sci 90:1378
Wunderlich W, Oekermann T, Miao L, Hue NT, Tanemura S, Tanemura M (2004) J Ceram Process Res 5:343
Shibata T, Irie H, Ohmori M, Nakajima A, Watanabe T, Hashimoto K (2004) Phys Chem Chem Phys 6:1359
Koelsch M, Cassaignon S, Guillemoles JF, Jolivet JP (2002) Thin Solid Films 403–404:312
Štengl V, Králová D (2011) Mater Chem Phys 129:794
Reyes-Coronado D, Rodriguez-Gattorno G, Espinosa-Pesqueira ME, Cab C, de Coss R, Oskam G (2008) Nanotechnology 19:145605
Mattsson A, Österlund L (2010) J Phys Chem C 114:14121
López-Muñoz MJ, Revilla A, Alcalde G (2015) Catal Today 240:138
Ohtani B, Prieto-Mahaney OO, Li D, Abe R (2010) J Photochem Photobiol A 216:179
Lin H, Li L, Zhao M, Huang X, Chen X, Li G, Yu R (2012) J Am Chem Soc 134:8328
Etacheri V, Di Valentin C, Schneider J, Bahnemann D, Pillai SC (2015) J Photochem Photobiol C 25:1
Fu C, Gong Y, Wu Y, Liu J, Zhang Z, Li C, Niu L (2016) Appl Surf Sci 379:83
Tosoni S, Fernandez Hevia D, Gonzalez Diaz O, Illas F (2012) J Phys Chem Lett 3:2269
Reddy PAK, Reddy PVL, Kim K-H, Kumar MK, Manvitha C, Shim J-J (2017) J Ind Eng Chem 53:253
Pikuda O, Garlisi C, Scandura G, Palmisano G (2017) J Catal 346:109
Ozer Y, Shin L, Felten Y, Oladipo A, Pikuda H, Muryn O, Casiraghi C, Palmisano C G (2017) J Environ Chem Eng 5:5091
Lei XF, Zhang ZN, Wu ZX, Piao YJ, Chen C, Li X, Xue XX, Yang H (2017) Sep Purif Technol 174:66
Tang X, Li D (2008) J Phys Chem C 112:5405
Pelaez M, Nolan NT, Pillai SC, Seery MK, Falaras P, Kontos AG, Dunlop PSM, Hamilton JWJ, Byrne JA, O’Shea K, Entezari MH, Dionysiou DD (2012) Appl Catal B 125:331
Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y (2001) Science 293:269
Ohno T, Akiyoshi M, Umebayashi T, Asai K, Mitsui T, Matsumura M (2004) Appl Catal A 265:115
Etacheri V, Michlits G, Seery MK, Hinder SJ, Pillai SC (2013) ACS Appl Mater Interfaces 5:1663
Feng H, Zhang M-H, Yu LE (2013) J Nanosci Nanotechnol 13:4981
Yin S, Aita Y, Komatsu M, Wang J, Tang Q, Sato T (2005) J Mater Chem 15:674
Hao H, Zhang J (2009) Microporous Mesoporous Mater 121:52
El-Sheikh SM, Zhang G, El-Hosainy HM, Ismail AA, O’Shea KE, Falaras P, Kontos AG, Dionysiou DD (2014) J Hazard Mater 280:723
Zhang G, Zhang YC, Nadagouda M, Han C, O’Shea K, El-Sheikh SM, Ismail AA, Dionysiou DD (2014) Appl Catal B 144:614
Mutuma BK, Shao GN, Kim WD, Kim HT (2015) J Colloid Interf Sci 442:1
Beranek R (2011) Adv Phys Chem 2011:1
Roy AM, De GC, Sasmal N, Bhattacharyya SS (1995) Int J Hydrog Energy 20:627
Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KSW (2015) Pure Appl Chem 87:1051
Etacheri V, Seery MK, Hinder SJ, Pillai SC (2012) Inorg Chem 51:7164
Wang P, Yap P-S, Lim T-T (2011) Appl Catal A 399:252
Wang Y, Huang Y, Ho W, Zhang L, Zou Z, Lee S (2009) J Hazard Mater 169:77
Gu DE, Lu Y, Yang BC, Hu YD (2008) Chem Commun 21:2453
Rengifo-Herrera JA, Pierzchała K, Sienkiewicz A, Forró L, Kiwi J, Pulgarin C (2009) Appl Catal B 88:398
Wei F, Ni L, Cui P (2008) J Hazard Mater 156:135
Wang X, Lim T-T (2010) Appl Catal B 100:355
Diwald O, Thompson TL, Zubkov T, Walck SD, Yates JT (2004) J Phys Chem B 108:6004
Sun H, Bai Y, Cheng Y, Jin W, Xu N (2006) Ind Eng Chem Res 45:4971
Lee HU, Lee Y-C, Lee SC, Park SY, Son B, Lee JW, Lim C-H, Choi C-J, Choi M-H, Lee SY, Oh Y-K, Lee J (2014) Chem Eng J 254:268
Fan D, Weirong Z, Zhongbiao W (2008) Nanotechnology 19:365607
Chen X, Burda C (2004) J Phys Chem B 108:15446
Sathish M, Viswanathan B, Viswanath RP, Gopinath CS (2005) Chem Mater 17:6349
György E, Pérez del Pino A, Serra P, Morenza JL (2003) Surf Coat Technol 173:265
Park J-Y, Lee C, Jung K-W, Jung D (2009) Bull Korean Chem Soc 30:402
Prasai B, Cai B, Underwood MK, Lewis JP, Drabold DA (2012) J Mater Sci 47:7515
Kramer B, Maschke K, Thomas P (1971) Phys Status Solidi B 48:635
Banerjee S, Pillai SC, Falaras P, O’Shea KE, Byrne JA, Dionysiou DD (2014) J Phys Chem Lett 5:2543
Li J-G, Tang C, Li D, Haneda H, Ishigaki T (2004) J Am Ceram Soc 87:1358
Perego C, Wang Y-H, Durupthy O, Cassaignon S, Revel R, Jolivet J-P (2012) ACS Appl Mater Interfaces 4:752
Sato T, Aita Y, Komatsu M, Yin S (2006) J Mater Sci 41:1433
García-Valenzuela JA (2017) Comments Inorg Chem 37:99
Li Z, Cong S, Xu Y (2014) ACS Catal 4:3273
Ohtani B (2014) Electrochemistry 82:414
Ohtani B (2014) Phys Chem Chem Phys 16:1788
Henderson MA (2011) Surf Sci Rep 66:185
Liu K-I, Su C-Y, Perng T-P (2015) RSC Adv 5:88367
Zhao Y, Huang X, Tan X, Yu T, Li X, Yang L, Wang S (2016) Appl Surf Sci 365:209
Rtimi S, Pulgarin C, Sanjines R, Kiwi J (2015) Appl Catal B 162:236
Krumova K, Cosa G (2016) In: Nonell S, Flors C (eds) Singlet oxygen: applications in biosciences and nanosciences, vol 1. The Royal Society of Chemistry, Cambridge, ch. 1
Houas A, Lachheb H, Ksibi M, Elaloui E, Guillard C, Herrmann JM (2001) Appl Catal B 31:145
Tomić N, Grujić-Brojčin M, Finčur N, Abramović B, Simović B, Krstić J, Matović B, Šćepanović M (2015) Mater Chem Phys 163:518
Luo B, Li Z, Xu Y (2015) RSC Adv 5:105999
Luís AM, Neves MC, Mendonça MH, Monteiro OC (2011) Mater Chem Phys 125:20
Yang W, Wen Y, Zeng D, Wang Q, Chen R, Wang W, Shan B (2014) J Mater Chem A 2:20770
Scanlon DO, Dunnill CW, Buckeridge J, Shevlin SA, Logsdail AJ, Woodley SM, Catlow CR, Powell MJ, Palgrave RG, Parkin IP, Watson GW, Keal TW, Sherwood P, Walsh A, Sokol AA (2013) Nat Mater 12:798
Cataldo S, Sartorio C, Giannazzo F, Scandurra A, Pignataro B (2014) Nanoscale 6:3566
Acknowledgements
This work was supported by Italian Ministry of Education, University and Research (project TECLA; Grant Number PON03PE_00214_1). The authors would like to acknowledge Michelangelo Scopelliti (Palermo University) for XPS spectra measurement, Salvatore Cataldo (Palermo University) for TOC measurement, Gang Wang (Utrecht University) for the precious help in the set-up of photocatalytic experiments and Jochem Wijten (Utrecht University) for the fruitful discussion on electrochemistry and the settlement of the related measurements.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Cataldo, S., Weckhuysen, B.M., Pettignano, A. et al. Multi-doped Brookite-Prevalent TiO2 Photocatalyst with Enhanced Activity in the Visible Light. Catal Lett 148, 2459–2471 (2018). https://doi.org/10.1007/s10562-018-2463-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-018-2463-8