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Catalytic Activity of Crystallographically Characterized Organic–Inorganic Hybrid Containing 1,5-Di-amino-pentane Tetrachloro Manganate with Perovskite Type Structure

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Abstract

Layered 2D organic–inorganic hybrid perovskite (OIHS) of the diammonium series, 1,5 di-aminepentane tetrachloro mangenate ([NH3–(CH2)5–NH3] MnCl4) was prepared by slow evaporation and reducing temperature method and characterized by single crystal X-ray diffraction analysis. Its structure consists of organic cation, [NH3(CH2)5NH3]+2 extended in a zigzag fashion and inorganic anion, [MnCl6]−2 where Mn2+ is coordinated by six Cl− ion in octahedral fashion. The organic and inorganic segments are alternately stacked along c-axis where inorganic layer is extended through corner-shared octahedra sandwiched by the di-aminopentane molecules. The layers (organic and inorganic) were connected to each other through N–H···Cl hydrogen bonds and van-der Waals interaction to build cation–anion–cation cohesion. The hybrid crystal had orthorhombic non-centrosymetric system having I212121 space group with unit cell parameters a = 7.1742(3) Å, b = 7.3817(3) Å, c = 23.9650(10) Å, V = 1269.13 Å3 and Z = 4. The hybrid exhibited excellent catalytic activity towards sulphide and alkene oxidation using aqueous H2O2 as an oxidant.

Graphical Abstract

OIHS of the diammonium series [NH3–(CH2)5–NH3] MnCl4; 1,5 di-aminepentane tetrachloro mangenate were prepared by slow evaporation and temperature decrease method, characterized by single crystal X-ray diffraction. This complex exhibits excellent catalytic activity towards sulphide oxidation and alkene oxidation using aqueous H2O2 as an oxidant.

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Acknowledgements

P.M. is thankful to the University Grant Commission (UGC) for funding in the form of Dr. D.S. Kothari post-doctoral research fellowship (Award no. F4-2/2006 (BSR)/CH/15–16/023). We sincerely thank Department of Chemistry of the University of Burdwan for infrastructural facilities. S.M.I. acknowledges the Council of Scientific and Industrial research, (CSIR, project reference no. 02(0284)/16/EMR-II), New Delhi, Govt. India, and Department of Science and Technology, Govt. of West Bengal (DST-W.B.), Project Reference Number 811(Sanc.) /ST/P/S&T/4G-8/2014, dated: 04/01/2016, for funding. We acknowledge Department of Science and Technology (DST) and University Grant Commission (UGC) New Delhi, India for providing support to the Department of Chemistry, University of Kalyani under PURSE, FIST and SAP program. S. K. A. is grateful to the financial support of Faculty of Science, Cairo University, Egypt.

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Authors and Affiliations

  1. Department of Chemistry, University of Kalyani, Nadia, Kalyani, 741235, India

    Paramita Mondal & Sk Manirul Islam

  2. Department of Physics, University of Cairo, Giza, 12613, Egypt

    Seham Kamal Abdel-Aal

  3. Egypt Nanotechnology center EGNC, Sheik Zayied city, Egypt

    Seham Kamal Abdel-Aal

  4. Department of Chemistry, The University of Burdwan, Burdwan, West Bengal, 713104, India

    Paramita Mondal & Debasis Das

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  1. Paramita Mondal
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  2. Seham Kamal Abdel-Aal
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  4. Sk Manirul Islam
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Correspondence to Seham Kamal Abdel-Aal, Debasis Das or Sk Manirul Islam.

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Mondal, P., Abdel-Aal, S.K., Das, D. et al. Catalytic Activity of Crystallographically Characterized Organic–Inorganic Hybrid Containing 1,5-Di-amino-pentane Tetrachloro Manganate with Perovskite Type Structure. Catal Lett 147, 2332–2339 (2017). https://doi.org/10.1007/s10562-017-2112-7

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