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The Effect of Metal Type on Hydrodeoxygenation of Phenol Over Silica Supported Catalysts

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Abstract

Different metals supported on SiO2 were tested for the hydrodeoxygenation of phenol. For Pt/SiO2, Pd/SiO2 and Rh/SiO2 catalysts, phenol is mainly tautomerized, followed by hydrogenation of the aromatic ring. The direct dehydroxylation of phenol followed by hydrogenolysis is favored over more oxophilic metals (Ru, Co and Ni).

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Acknowledgments

Camila A. Teles and Jerusa R. de Lima thank CAPES (Coordenação de Aperfeiçoamento de Pessoal de Ensino Superior) for the scholarship received.

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Authors and Affiliations

  1. Catalysis Division, National Institute of Technology, Rio de Janeiro, 20081-312, Brazil

    Camila A. Teles, Raimundo C. Rabelo-Neto & Fabio B. Noronha

  2. Chemical Engineering Department, Military Institute of Engineering, Praça Gal. Tiburcio 80, Rio de Janeiro, 22290-270, Brazil

    Camila A. Teles & Fabio B. Noronha

  3. Chemical Engineering Department, Fluminense Federal University, Rua Passo da Pátria 156, Niterói, 24210-240, Brazil

    Jerusa R. de Lima & Lisiane V. Mattos

  4. School of Chemical, Biological, and Materials Engineering, Center for Biomass Refining, The University of Oklahoma, Norman, OK, 73019, USA

    Daniel E. Resasco

Authors
  1. Camila A. Teles
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  2. Raimundo C. Rabelo-Neto
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  3. Jerusa R. de Lima
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  4. Lisiane V. Mattos
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  6. Fabio B. Noronha
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Correspondence to Fabio B. Noronha.

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Teles, C.A., Rabelo-Neto, R.C., de Lima, J.R. et al. The Effect of Metal Type on Hydrodeoxygenation of Phenol Over Silica Supported Catalysts. Catal Lett 146, 1848–1857 (2016). https://doi.org/10.1007/s10562-016-1815-5

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  • DOI: https://doi.org/10.1007/s10562-016-1815-5

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