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Metathesis of C5–C8 Terminal Olefins on Re2O7/Al2O3 Catalysts

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Abstract

Primary products of the interaction of terminal olefins C5–C8 with Re2O7/Al2O3 catalysts are established. The rupture of the C=C bond of the olefin occurs with formation of a carbene localized at a rhenium ion, with the alkylidene fragment in the produced carbene being the CH2=group of the terminal alkene molecule. Thus M=CH2 species and lower normal α-olefins are formed.

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Acknowledgments

LMK gratefully acknowledges the financial support of the Ministry of Education and Science of the Russian Federation in the framework of Increase Competitiveness Program of NUST « MISiS » (No K1-2015-045).

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Authors and Affiliations

  1. N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prospect, Moscow, 119991, Russia

    Leonid M. Kustov, Daniil B. Furman & Aleksandra P. Barkova

  2. Department of Chemistry, Moscow State University, Leninskie Gory 1, bldg. 3, Moscow, 119992, Russia

    Leonid M. Kustov

  3. National University of Science and Technology «MISiS», Leninsky prosp. 4, Moscow, Russia

    Leonid M. Kustov

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  1. Leonid M. Kustov
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  2. Daniil B. Furman
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  3. Aleksandra P. Barkova
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Correspondence to Leonid M. Kustov.

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Kustov, L.M., Furman, D.B. & Barkova, A.P. Metathesis of C5–C8 Terminal Olefins on Re2O7/Al2O3 Catalysts. Catal Lett 146, 1033–1039 (2016). https://doi.org/10.1007/s10562-016-1698-5

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  • DOI: https://doi.org/10.1007/s10562-016-1698-5

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