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Effects of Water Addition on CO Hydrogenation Over Zinc-Containing Spinel-Supported Cobalt Catalyst

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Abstract

Literature about water addition over AB2O4 spinel-supported cobalt CO hydrogenation catalysts is sparse. A comparative water addition experiment was conducted over Co/ZnAl2O4·Al2O3 catalyst. Water addition may cause lower C1 (i.e., CH4) hydrocarbon distribution, lower C2–C4 hydrocarbon distribution, higher C5+ hydrocarbon distribution and higher C2–C4 olefin/paraffin ratio than the control test without water addition. Possibly, as a product of Fischer–Tropsch synthesis, water might have an autocatalytic effect for the FTS process to generate longer chain hydrocarbons via its facilitation of C–C coupling. The Co/ZnAl2O4·Al2O3 catalyst exhibits good resistance against steam sintering.

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Acknowledgments

We thank the National Natural Science Foundation of China (NSFC No. U1204202) for financial support. We also thank Henan Provincial Foundation for Scientific and Technological Program (No. 124300510041).

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Authors and Affiliations

  1. Henan Provincial Key Laboratory of Surface and Interface Science, School of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou, 450002, China

    Zhenxin Liu, Yingying Xue, Depeng Wu, Yu Xing & Shaoming Fang

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  1. Zhenxin Liu
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  2. Yingying Xue
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  3. Depeng Wu
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  4. Yu Xing
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  5. Shaoming Fang
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Correspondence to Yu Xing or Shaoming Fang.

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Liu, Z., Xue, Y., Wu, D. et al. Effects of Water Addition on CO Hydrogenation Over Zinc-Containing Spinel-Supported Cobalt Catalyst. Catal Lett 145, 1941–1947 (2015). https://doi.org/10.1007/s10562-015-1613-5

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  • DOI: https://doi.org/10.1007/s10562-015-1613-5

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