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Magnetic Carbon Nanofiber Networks as Support for Ionic Liquid Based Catalyst

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Abstract

In this work, the ionic liquid (IL) 1-hexyl-3-methyl-imidazolium bromide (HMIm.Br) containing Pd suspended nanoparticles was supported on a nanostructured magnetically recoverable carbon nanofiber network. The magnetic material was prepared by a simple reaction of ethanol directly with a nanostructured hematite. SEM, XRD, Mössbauer, Raman, TG/DTA, BET surface area and magnetization analyses suggested that the network is based on carbon nanofibers with carbon coated magnetic Fe nanoparticles. These magnetic networks offer a high exposed carbon fiber area, which has a good interaction with the IL to form a thin layer. Preliminary studies with a Pd dispersed in supported IL as catalyst for the hydrogenation of 1,5-cyclooctadiene showed a membrane effect, which leads to an important increase on the selective hydrogenation of 1,5-cyclooctadiene to cyclooctene.

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Acknowledgments

The authors acknowledge the financial support provided from FAPEMIG, PRPq/UFMG, CNPq, CAPES, and PETROBRAS.

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Authors and Affiliations

  1. Departamento de Química, Instituto de Ciências Exatas, Universidade Federal de Minas Gerais, Belo Horizonte, MG, 31270-901, Brazil

    Evelisy C. O. Nassor, Henrique S. Oliveira, Flávia C. C. Moura, Eduardo N. dos Santos, Rochel M. Lago & Maria Helena Araujo

  2. Universidade Federal de Viçosa, Campus Florestal, Florestal, MG, 35690-000, Brazil

    Juliana C. Tristão

Authors
  1. Evelisy C. O. Nassor
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  2. Juliana C. Tristão
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  3. Henrique S. Oliveira
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  4. Flávia C. C. Moura
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  5. Eduardo N. dos Santos
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  6. Rochel M. Lago
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  7. Maria Helena Araujo
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Corresponding author

Correspondence to Maria Helena Araujo.

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Nassor, E.C.O., Tristão, J.C., Oliveira, H.S. et al. Magnetic Carbon Nanofiber Networks as Support for Ionic Liquid Based Catalyst. Catal Lett 145, 505–510 (2015). https://doi.org/10.1007/s10562-014-1374-6

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  • DOI: https://doi.org/10.1007/s10562-014-1374-6

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