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Catalytic CO Oxidation Over Gold Nanoparticles: Support Modification by Monolayer- and Submonolayer-Dispersed Sb2O3

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Abstract

A new kind of heterostructured mesoporous materials for supporting gold nanoparticles was developed by surface modification of mesoporous cellulous foam silica (MCF) with antimony trioxide (Sb2O3) in a monolayer/submonolayer state through a spontaneous dispersion process at 450 °C for 24 h. Gold nanoparticles were well stabilized on the surface of MCF–Sb2O3, exhibiting not only catalytic activity for CO oxidation even below room temperature but also good catalytic stability without the growth of Au nanoparticles after a steady-state reaction for 30 h.

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References

  1. Xie XW, Li Y, Liu ZQ, Haruta M, Shen WJ (2009) Nature 458:746

    Article  CAS  Google Scholar 

  2. Zhang TY, Wang SP, Yu Y, Su Y, Guo XZ, Wang SR, Zhang SM, Wu SH (2008) Catal Commun 9:1259

    Article  CAS  Google Scholar 

  3. Oh SH, Hoflund GB (2007) J Catal 245:35

    Article  CAS  Google Scholar 

  4. Mergler YJ, Hoebink J, Nieuwenhuys BE (1997) J Catal 167:305

    Article  CAS  Google Scholar 

  5. Moreau F, Bond GC, Taylor AO (2004) Chem Commun 14:1642

    Article  Google Scholar 

  6. Kahlich MJ, Gasteiger HA, Behm RJ (1999) J Catal 182:430

    Article  CAS  Google Scholar 

  7. Date M, Okumura M, Tsubota S, Haruta M (2004) Angew Chem Int Ed 43:2129

    Article  CAS  Google Scholar 

  8. Bethke GK, Kung HH (2000) Appl Catal A 194:43

    Article  Google Scholar 

  9. Haruta M, Date M (2001) Appl Catal A 222:427

    Article  CAS  Google Scholar 

  10. Valden M, Lai X, Goodman DW (1998) Science 281:1647

    Article  CAS  Google Scholar 

  11. Chen MS, Goodman DW (2004) Science 306:252

    Article  CAS  Google Scholar 

  12. Arrii S, Morfin F, Renouprez AJ, Rousset JL (2004) J Am Chem Soc 126:1199

    Article  CAS  Google Scholar 

  13. Comotti M, Li WC, Spliethoff B, Schüth F (2006) J Am Chem Soc 128:917

    Article  CAS  Google Scholar 

  14. Okumura M, Nakamura S, Tsubota S, Nakamura T, Azuma M, Haruta M (1998) Catal Lett 51:53

    Article  CAS  Google Scholar 

  15. Wu SH, Zheng XC, Wang SR, Han DZ, Huang WP, Zhang SM (2004) Catal Lett 96:49

    Article  CAS  Google Scholar 

  16. Wolf A, Schüth F (2002) Appl Catal A 226:1

    Article  CAS  Google Scholar 

  17. Moreau F, Bond GC (2006) Appl Catal A 302:110

    Article  CAS  Google Scholar 

  18. Knell A, Barnickel P, Baiker A, Wokaun A (1992) J Catal 137:306

    Article  CAS  Google Scholar 

  19. Konova P, Naydenov A, Tabakova T, Mehandjiev D (2004) Catal Commun 5:537

    Article  CAS  Google Scholar 

  20. Haruta M (2002) CATTECH 6:102

    Article  CAS  Google Scholar 

  21. Choudhary TV, Goodman DW (2002) Top Catal 21:25

    Article  CAS  Google Scholar 

  22. Kung HH, Kung MC, Costello CK (2003) J Catal 216:425

    Article  CAS  Google Scholar 

  23. Hashmi ASK, Hutchings GJ (2006) Angew Chem Int Ed 45:7896

    Article  Google Scholar 

  24. Goodman DW (2005) Catal Lett 99:1

    Article  CAS  Google Scholar 

  25. Tauster SJ, Fung SC, Garten RL (1978) J Am Chem Soc 100:170

    Article  CAS  Google Scholar 

  26. Sanchez A, Abbet S, Heiz U, Schneider WD, Hakkinen H, Barnett RN, Landman U (1999) J Phys Chem A 103:9573

    Article  CAS  Google Scholar 

  27. Heiz U, Schneider WD (2000) J Phys D 33:R85

    Article  CAS  Google Scholar 

  28. Si R, Tao J, Evans J, Park JB, Barrio L, Hanson JC, Zhu Y, Hrbek J, Rodriguez JA (2012) J Phys Chem C 116:23547

    Article  CAS  Google Scholar 

  29. Park JB, Graciani J, Evans J, Stacchiola D, Senanayake SD, Barrio L, Liu P, Sanz JF, Hrbek J, Rodriguez JA (2010) J Am Chem Soc 132:356

    Article  CAS  Google Scholar 

  30. Liu ZP, Jenkins SJ, King DA (2004) Phys Rev Lett 93:156102

    Article  Google Scholar 

  31. Yan WF, Mahurin SM, Chen B, Overbury SH, Dai S (2005) J Phys Chem B 109:15489

    Article  CAS  Google Scholar 

  32. Ma Z, Brown S, Overbury SH, Dai S (2007) Appl Catal A 327:226

    Article  CAS  Google Scholar 

  33. Tian C, Chai SH, Zhu X, Wu Z, Binder A, Bauer JC, Brwon S, Chi M, Veith GM, Guo Y, Dai S (2012) J Mater Chem 22:25227

    Article  CAS  Google Scholar 

  34. Tian C, Chai SH, Mullins DR, Zhu X, Binder A, Guo Y, Dai S (2013) Chem Commun 49:3464

    Article  CAS  Google Scholar 

  35. Xie YC, Tang YQ (1990) Adv Catal 37:1

    CAS  Google Scholar 

  36. Schmidt-Winkel P, Lukens WW, Yang PD, Margolese DI, Lettow JS, Ying JY, Stucky GD (2000) Chem Mater 12:686

    Article  CAS  Google Scholar 

  37. Yan W, Brown S, Pan Z, Mahurin SM, Overbury SH, Dai S (2006) Angew Chem Int Ed 45:3614

    Article  CAS  Google Scholar 

  38. Araki H, Fukuoka A, Sakamoto Y, Inagaki S, Sugimoto N, Fukushima Y, Ichikawa M (2003) J Mol Catal A 199:95

    Article  CAS  Google Scholar 

  39. Schmidt-Winkel P, Lukens WW, Zhao DY, Yang PD, Chmelka BF, Stucky GD (1999) J Am Chem Soc 121:254

    Article  CAS  Google Scholar 

  40. Xu H, Chu W, Luo J, Zhang T (2011) Chem Eng J 170:419

    Article  CAS  Google Scholar 

  41. Haruta M (2003) Chem Rec 3:75

    Article  CAS  Google Scholar 

  42. Wang SR, Huang J, Zhao YQ, Wang SP, Wang XY, Zhang TY, Wu SH, Zhang SM, Huang WP (2006) J Mol Catal A 259:245

    Article  CAS  Google Scholar 

  43. Glaspell G, Hassan HMA, Elzatahry A, Fuoco L, Radwan NRE, El-Shall MS (2006) J Phys Chem B 110:21387

    Article  CAS  Google Scholar 

  44. Zhu H, Ma Z, Clark JC, Pan Z, Overbury SH, Dai S (2007) Appl Catal A 326:89

    Article  CAS  Google Scholar 

  45. Bond GC, Thompson DT (2000) Gold Bull 33:41

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The research was sponsored by the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, US Department of Energy, under Contract No. De-AC05-00OR22725 with Oak Ridge National Laboratory, managed and operated by UT-Battelle, LLC. Lin Li expresses gratitude for the financial support from the South-Central University for Nationalities (No. CZZ12002).

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Authors and Affiliations

  1. Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, College of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan, 430074, China

    Lin Li

  2. Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA

    Song-Hai Chai, Andrew Binder & Sheng Dai

  3. Department of Chemistry, University of Tennessee, Knoxville, TN, 37996-1600, USA

    Lin Li, Suree Brown & Sheng Dai

  4. Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA

    Gabriel M. Veith

Authors
  1. Lin Li
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  2. Song-Hai Chai
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  3. Andrew Binder
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  4. Suree Brown
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  5. Gabriel M. Veith
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  6. Sheng Dai
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Correspondence to Lin Li or Sheng Dai.

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Li, L., Chai, SH., Binder, A. et al. Catalytic CO Oxidation Over Gold Nanoparticles: Support Modification by Monolayer- and Submonolayer-Dispersed Sb2O3 . Catal Lett 144, 912–919 (2014). https://doi.org/10.1007/s10562-014-1239-z

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  • DOI: https://doi.org/10.1007/s10562-014-1239-z

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