Abstract
Ozone is found to promote the monochlorobenzene (CB) catalytic oxidation over carbon nanotubes supported copper oxide composite up to reaction temperature of 300 °C. Especially at 250 °C, a CB conversion of 99 %, together with a CO2 selectivity of 98 %, was observed. The selective adsorption of CB, the promotion of Cu+ to Cu2+ oxidation, and the combination of O3 and high temperature activated gas phase O2 are all considered to attribute to the high CB conversion and CO2 selectivity at temperature above 250 °C.
Graphical Abstract
Effects of O3 on catalytic oxidation of CB over CuOX/CNTs were studied. A CB conversion of 99 % and a CO2 selectivity of 98 % were achieved at 250 °C, which could be mainly attributed to the synergy between the CB oxidation by O3 and activated O2.
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Acknowledgments
This work was supported by the Environmentally Sustainable Management of Medical Wastes in China (Contract No. C/V/S/10/251), the National Natural Foundation of Zhejiang Province, China (Grant No. Z4080070), and Zhejiang Province Environmental Protection Science Research Plan of China (Grant No. 2011B14).
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Chen, R., Jin, D., Yang, H. et al. Ozone Promotion of Monochlorobenzene Catalytic Oxidation Over Carbon Nanotubes-Supported Copper Oxide at High Temperature. Catal Lett 143, 1207–1213 (2013). https://doi.org/10.1007/s10562-013-1059-6
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DOI: https://doi.org/10.1007/s10562-013-1059-6