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Palladium Supported on Functionalized Mesoporous Silica as an Efficient Catalyst for Suzuki–Miyaura Coupling Reaction

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Abstract

Mesoporous SBA-15 was modified with organic functional groups by co-condensation method. The functionalized mesoporous silica can be loaded with palladium and the resulting material used as a catalyst for the Suzuki–Miyaura coupling reactions. Highly dispersed and uniform palladium nanoparticles could be detected using transmission electron microscopy. The Pd-SBA-15 nanocomposite with controlled molar ratio of amino groups to palladium exhibits an excellent catalytic activity and low Pd leaching for the Suzuki–Miyaura coupling reaction. The catalyst can also be reused at least six recycles in air with only a minor loss of activity.

Graphical Abstract

Mesoporous SBA-15 was modified with organic functional groups by co-condensation method. The functionalized mesoporous silica can be loaded with palladium and the resulting material used as a catalyst for the Suzuki–Miyaura coupling reactions. Highly dispersed and uniform palladium nanoparticles could be detected using transmission electron microscopy. The Pd-SBA-15 nanocomposite with controlled molar ratio of amino groups to palladium exhibits an excellent catalytic activity and low Pd leaching for the Suzuki–Miyaura coupling reaction. The catalyst can also be reused at least six recycles in air with only a minor loss of activity.

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Acknowledgments

This work was supported by the Fundamental Research Funds for the Central Universities, China. (Grant No. zyz2012057), Natural Science Foundation of Gan Su Province (Grant No. 0803RJZA008), China.

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Authors and Affiliations

  1. Key Laboratory for Electronic Materials of the State National Affairs Commission of PRC, Northwest University for Nationality, Lanzhou, 730030, Gansu, China

    Guoheng Zhang & Peiyu Wang

  2. College of Bailie Engineering and Technology, Lanzhou City University, Lanzhou, 730070, China

    Xiufang Wei

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  1. Guoheng Zhang
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  2. Peiyu Wang
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  3. Xiufang Wei
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Correspondence to Guoheng Zhang.

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Zhang, G., Wang, P. & Wei, X. Palladium Supported on Functionalized Mesoporous Silica as an Efficient Catalyst for Suzuki–Miyaura Coupling Reaction. Catal Lett 143, 1188–1194 (2013). https://doi.org/10.1007/s10562-013-1054-y

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  • DOI: https://doi.org/10.1007/s10562-013-1054-y

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