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New Simple Synthesis Route for Decatungstate Hybrids: Novel Thermo-Regulated Phase Transfer Catalysts for Selective Oxidation of Alcohols

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Abstract

A generalized synthesis method for decatungstate hybrids from bisulfate-based acidic ionic liquids was reported. N-butylpyridinium decatungstate [bPy]4W10O32 and 1-butyl-3-methylimidazolium decatungstate [bmIm]4W10O32 were synthesized and have been demonstrated to be good thermo-regulated phase transfer catalysts in an organic-solvent-free selective oxidation of alcohols under mild conditions. Advantages of heterogeneous and homogeneous catalysis are combined here, provided good self-separated and ease-of-recycling catalysts.

Graphical Abstract

Decatungstates hybrids were synthesized in high yields directly from bisulfate-based ionic liquids, and used as novel catalysts in selective oxidation of alcohols to aldehydes or ketones. A homogeneous phase can be induced during reaction, and the catalyst could be self separated after reaction.

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Acknowledgments

The authors are grateful for the financial supports from the National Natural Science Foundation of China (No. 21103077), Program for New Century Excellent Talents in University(NCET) (No. NCET-11-1011), Liaoning Excellent Talents in University (Nos. LR201024 and LJQ2011035), Natural Science Foundation of Liaoning Province (Nos. 201102120 and 201202123) and Foundation of the Education Department of Liaoning Province (Nos. 2010243 and L2012128).

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Authors and Affiliations

  1. College of Chemistry and Materials Science, Liaoning Shihua University, Fushun, 113001, Liaoning, People’s Republic of China

    Dan Liu, Jianzhou Gui, Feng lu & Zhaolin Sun

  2. Green Chemistry Division, Korea Research Institute of Chemical Technology, Daejeon, 305-343, Republic of Korea

    Dan Liu & Yong-Ki Park

Authors
  1. Dan Liu
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  2. Jianzhou Gui
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  3. Feng lu
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  4. Zhaolin Sun
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  5. Yong-Ki Park
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Corresponding authors

Correspondence to Jianzhou Gui or Yong-Ki Park.

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Liu, D., Gui, J., lu, F. et al. New Simple Synthesis Route for Decatungstate Hybrids: Novel Thermo-Regulated Phase Transfer Catalysts for Selective Oxidation of Alcohols. Catal Lett 142, 1330–1335 (2012). https://doi.org/10.1007/s10562-012-0911-4

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  • DOI: https://doi.org/10.1007/s10562-012-0911-4

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