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Cu/SBA-15 is an Efficient Solvent-Free and Acid-Free Catalyst for the Rearrangement of Benzaldoxime into Benzamide

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Abstract

Cu/SBA-15 catalysts with various Cu loadings in the range of 5–20 wt% were prepared by an impregnation method and characterized by N2 adsorption, X-ray diffraction, temperature programmed reduction and X-Ray photoelectron spectroscopic techniques. Cu/SBA-15 catalysts are found to be highly active and selective for the Beckmann rearrangement of benzaldoxime into benzamide under solvent-free and acid-free conditions.

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Acknowledgments

The authors Mr. G. Saidulu and N. Anand acknowledge the Council of Scientific and Industrial Research, New Delhi for the award of research fellowship.

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Authors and Affiliations

  1. Catalysis Laboratory, Indian Institute of Chemical Technology, Hyderabad, 500 607, India

    Ganji Saidulu, Narani Anand, Kamaraju Seetha Rama Rao & David Raju Burri

  2. Department of Chemistry, Laboratory of Nano-green Catalysis, Inha University, Incheon, 402-751, Korea

    Abhishek Burri & Sang-Eon Park

Authors
  1. Ganji Saidulu
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  2. Narani Anand
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  3. Kamaraju Seetha Rama Rao
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  4. Abhishek Burri
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  5. Sang-Eon Park
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  6. David Raju Burri
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Corresponding authors

Correspondence to Sang-Eon Park or David Raju Burri.

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Saidulu, G., Anand, N., Rao, K.S.R. et al. Cu/SBA-15 is an Efficient Solvent-Free and Acid-Free Catalyst for the Rearrangement of Benzaldoxime into Benzamide. Catal Lett 141, 1865–1871 (2011). https://doi.org/10.1007/s10562-011-0713-0

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