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1-Butene Cracking to Propene on High Silica HMCM-22: Relations Between Product Distribution and Feed Conversion Under Various Temperatures

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Abstract

HMCM-22 zeolite with a high Si/Al2 ratio (158) was applied to the 1-butene cracking reaction in a fixed-bed reactor. On basis of the product distribution, the main reaction pathways of C4 alkenes catalytic transforming on HMCM-22 were proposed. Also, the preferences of the reaction pathways influenced by the temperature and conversion level were discussed, which could provide good guidance on enhancing the propene production.

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Acknowledgments

The authors would like to thank the National Basic Research Program (National 973 Project) of China (No. 2005CB221403 and No. 2009CB623501) and the National Natural Science Foundation of China (No. 20773120) for financial support.

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Authors and Affiliations

  1. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023, Dalian, Liaoning, People’s Republic of China

    Guoliang Xu, Xiangxue Zhu, Sujuan Xie, Xiujie Li, Shenglin Liu & Longya Xu

  2. Graduate University of Chinese Academy of Sciences, 100049, Beijing, China

    Guoliang Xu

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  1. Guoliang Xu
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  2. Xiangxue Zhu
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  3. Sujuan Xie
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  4. Xiujie Li
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  5. Shenglin Liu
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Correspondence to Longya Xu.

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Xu, G., Zhu, X., Xie, S. et al. 1-Butene Cracking to Propene on High Silica HMCM-22: Relations Between Product Distribution and Feed Conversion Under Various Temperatures. Catal Lett 130, 204–210 (2009). https://doi.org/10.1007/s10562-009-9864-7

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  • DOI: https://doi.org/10.1007/s10562-009-9864-7

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