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Selective Oxidation of Isobutane and Isobutene to Methacrolein over Te–Mo Mixed Oxide Catalysts

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Abstract

A series of Te–Mo–O catalysts were prepared by decomposing (NH4)4TeMo6O22 · 2H2O telluromolybdate under different conditions and tested for the oxidation of isobutane and isobutene. Characterization results (XRD, FTIR, TG, TPR, XPS, and BET) showed that their structure and properties depend on calcination conditions. Catalytic tests showed that molybdenum may be the key element for the activation of isobutane, whereas the selective oxidation of isobutene to methacrolein (MAL) might proceed mainly on the surface of the TeMo-containing crystalline phase. Thus, relatively high selectivities and yields of MAL and methacrylic acid (MAA) can be obtained over these specially designed catalysts.

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References

  1. Guan J, Jing S, Wu S, Xu H, Wang Z, Kan Q (2007) React Kinet Catal Lett 90:27

    Article  CAS  Google Scholar 

  2. Guan J, Jia M, Jing S, Wang Z, Xing L, Xu H, Kan Q (2006) Catal Lett 108:125

    Article  CAS  Google Scholar 

  3. Guan JQ, Wu SJ, Jia MJ, Huang JH, Jing SB, Xu HY, Wang ZL, Zhu WC, Xing HJ, Wang HS, Kan QB (2007) Catal Commun 8:1219

    Article  CAS  Google Scholar 

  4. Guan JQ, Wu SJ, Wang HS, Jing SB, Wang GJ, Zhen KJ, Kan QB (2007) J Catal 251:354

    Article  CAS  Google Scholar 

  5. Andre D, Belletti A, Cavani F, Degrand H, Dubois J-L, Lucarelli C, Trifirò F (2004) DGMK Tagungsbericht 289

  6. André D, Belletti A, Cavani F, Degrand H, Dubois J-L, Trifirò F (2005) Stud Surf Sci Catal 155:57

    Article  Google Scholar 

  7. Ueda W, Oshihara K, Vitry D, Hisano T, Kayashima Y (2002) Catal Surv Japan 6:33

    Article  CAS  Google Scholar 

  8. Botella P, López Nieto JM, Solsona B, Mifsud A, Márquez F (2002) J Catal 209:445

    Article  CAS  Google Scholar 

  9. Aouine M, Dubois JL, Millet JMM (2001) Chem Commun 1180

  10. Grasselli RK, Burrington JD, Buttrey DJ, DeSanto P Jr, Lugmair CG, Volpe AF Jr, Weingand T (2003) Top Catal 23:5

    Article  CAS  Google Scholar 

  11. Millet JMM, Roussel H, Pigamo A, Dubois JL, Jumas JC (2002) Appl Catal A 232:77

    Article  CAS  Google Scholar 

  12. Bart JCJ, Bossi A, Petrini G, Battiston G, Castellan A, Covini R (1983) Appl Catal 6:85

    Article  CAS  Google Scholar 

  13. Grzybowska B, Mazurkiewicz A, Stoczyński J (1985) Appl Catal 13:223

    Article  CAS  Google Scholar 

  14. Botella P, López Nieto JM, Solsona B (2002) J Mol Catal A: Chem 184:335

    Article  CAS  Google Scholar 

  15. Zhiznevskii VN, Fedevich YV, Sulima IM (1971) Petro Chem USSR 11:157

    Article  Google Scholar 

  16. Balraj V, Vidyasagar K (1999) Inorg Chem 38:1394

    Article  CAS  Google Scholar 

  17. Vande Putte D, Hoonrnaerts S, Thyrion FC, Ruiz P, Delmon B (1996) Catal Today 32:255

    Article  Google Scholar 

  18. Dimitriev Y, Bart JCJ, Dimitrov V, Arnaudov M (1981) Z Anorg Allg Chem 479:229

    Article  CAS  Google Scholar 

  19. Zhu Y, Lu W, Li H, Wan H (2007) J Catal 246:382

    Article  CAS  Google Scholar 

  20. Parmaliana A, Arena F, Frusteri F (1997) Stud Sturf Sci Catal 110:347

    Article  CAS  Google Scholar 

  21. Adamski A, Sojka Z, Dyrek K (1999) Langmuir 15:5733

    Article  CAS  Google Scholar 

  22. Guan JQ, Wang GJ, Jing SB, Wang ZL, Kan QB (2006) Pol J Chem 80:1397

    CAS  Google Scholar 

  23. Botto IL, Cabello CI, Thomas HJ (1997) Mater Chem Phys 47:37

    Article  CAS  Google Scholar 

  24. Forzatti P, Trifiró F, Villa PL (1978) J Catal 55:52

    Article  CAS  Google Scholar 

  25. Weng LT, Ruiz P, Delmon B, Duprez D (1989) J Mol Catal 52:349

    Article  CAS  Google Scholar 

  26. Yu Adzhmov K, Agaguseinova MM, Khanmamedova AK, Alkhazov TG (1979) Kinet Catal 20:1036

    Google Scholar 

  27. Botella P, Concepción P, López Nieto JM, Moreno Y (2005) Catal Today 99:51

    Article  CAS  Google Scholar 

Download references

Acknowledgments

We acknowledge the financial supports from the National Basic Research Program of China (2004CB217804) and the National Natural Science Foundation of China (20673046).

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130023, People’s Republic of China

    Jingqi Guan, Cheng Xu, Zhuqian Wang, Ying Yang, Bo Liu, Fanpeng Shang, Yanqiu Shao & Qiubin Kan

  2. Department of Chemistry, Mudanjiang Normal College, Mudanjiang, 157012, People’s Republic of China

    Yanqiu Shao

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  1. Jingqi Guan
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  2. Cheng Xu
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  3. Zhuqian Wang
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  4. Ying Yang
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  7. Yanqiu Shao
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  8. Qiubin Kan
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Correspondence to Qiubin Kan.

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Guan, J., Xu, C., Wang, Z. et al. Selective Oxidation of Isobutane and Isobutene to Methacrolein over Te–Mo Mixed Oxide Catalysts. Catal Lett 124, 428–433 (2008). https://doi.org/10.1007/s10562-008-9496-3

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  • DOI: https://doi.org/10.1007/s10562-008-9496-3

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