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A Comparison Study on the Structure and Performance of Mo–V–O and Mo–V–Te–O Catalysts Synthesized Hydrothermally with Ultrasonic Pretreatment for Propane Oxidation

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Abstract

The Mo1.00V0.80O n and Mo1.00VαTe0.17O n (α = 0.40–1.00) catalysts were prepared hydrothermally with ultrasonic pretreatment for propane partial oxidation. The fabricated catalysts were characterized by BET, XRD, Raman, XPS, EPR, SEM, H2–TPR, and NH3-calorimetric techniques. It is revealed that the content of vanadium in the catalysts is crucial for the generation of phase structure essential for good performance. The role of Te in the catalytic system and the effect of ultrasonic treatment during catalyst fabrication on catalyst properties are interpreted based on the characterization and reaction results obtained.

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Acknowledgments

We thank NSFC (20673052), HKBU (FRG/03-04/II-17), and JSNSF (BK2006112) for financial supports.

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Correspondence to Weijie Ji or Chak-Tong Au.

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Yang, X., Zhang, W., Feng, R. et al. A Comparison Study on the Structure and Performance of Mo–V–O and Mo–V–Te–O Catalysts Synthesized Hydrothermally with Ultrasonic Pretreatment for Propane Oxidation. Catal Lett 124, 288–296 (2008). https://doi.org/10.1007/s10562-008-9451-3

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  • DOI: https://doi.org/10.1007/s10562-008-9451-3

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