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Creation of a Monomeric Ag Species on the Surface of γ-ZrP as an Efficient Heterogeneous Catalyst for the Selective Oxidation of Cycloolefins

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Abstract

A hybrid complex Zr(PO4)(AgHPO4) was prepared by ion-exchange and its activity was examined on the allylic oxidation of cycloolefins using tert-butylhydroperoxide (TBHP) as oxidant under argon atmosphere. Under these reaction conditions, attack of the activated C–H bond was preferred instead of the epoxidation of C=C bond, yielding enols as the main products, this is a novel highly active/selective and reusable heterogeneous catalyst.

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Authors and Affiliations

  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China

    Junhua Liu, Fang Wang & Xianlun Xu

  2. Graduate School, Chinese Academy of Sciences, Beijing, 100049, China

    Junhua Liu & Fang Wang

Authors
  1. Junhua Liu
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  2. Fang Wang
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  3. Xianlun Xu
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Correspondence to Xianlun Xu.

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Liu, J., Wang, F. & Xu, X. Creation of a Monomeric Ag Species on the Surface of γ-ZrP as an Efficient Heterogeneous Catalyst for the Selective Oxidation of Cycloolefins. Catal Lett 120, 106–110 (2008). https://doi.org/10.1007/s10562-007-9259-6

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  • DOI: https://doi.org/10.1007/s10562-007-9259-6

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