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Photodegradation of Some Dyes Over Ce/FSM-16 Catalyst Under Solar Light

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Abstract

Ce doped FSM-16 (Ce/FSM-16) was synthesized by templating method and its photoactivity for the degradation of methyl violet, safranine T, fuchsin basic and methylthionine chloride under solar light was studied for the first time. Ce/FSM-16 had very high surface area (863 m2 g−1) and pore volume (0.73 cm3 g−1). Doping cerium ions appears important in bringing about sunlight photocatalytic activity. The photoactivity of Ce/FSM-16 is comparable with that of Degussa P25 under solar light. By contrast, undoped FSM-16 exhibited very strong adsorption capacity for these dyes, but did not exhibit significant photoactivity for them. The degradation of dyes catalyzed by Ce/FSM-16 under solar light followed a radical-type mechanism.

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Acknowledgments

The authors thank the National Natural Science Foundation of China (Project 20463003), Natural Science Foundation of Yunnan Province (Project 2004E0003Z) for financial support. We also thank Center for Advanced Studies of Medicinal and Organic Chemistry, Yunnan University for partial financial support.

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Authors and Affiliations

  1. Department of Applied Chemistry, Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Yunnan University, Kunming, 650091, P.R. China

    Ying Wu, Junjie Li & Jiaqiang Wang

  2. Provincial Key Laboratory of Rural Energy Engineering, Yunnan Normal University, Kunming, 650092, P.R. China

    Shiqing Liu

  3. The Environmental Monitoring Station of Dali, Dali, 671000, P.R. China

    Yongfu Zuo

Authors
  1. Ying Wu
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  2. Shiqing Liu
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  3. Yongfu Zuo
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  4. Junjie Li
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  5. Jiaqiang Wang
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Correspondence to Jiaqiang Wang.

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Wu, Y., Liu, S., Zuo, Y. et al. Photodegradation of Some Dyes Over Ce/FSM-16 Catalyst Under Solar Light. Catal Lett 119, 245–251 (2007). https://doi.org/10.1007/s10562-007-9224-4

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  • DOI: https://doi.org/10.1007/s10562-007-9224-4

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