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Formation of brownmillerite type calcium ferrite (Ca2Fe2O5) and catalytic properties in propylene combustion

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Abstract

Several types of calcium ferrite base catalysts (Ca/Fe = 0.33–3) for propylene (C3H6) combustion were prepared. Calcium ferrite catalyst with brownmillerite crystal structure provided catalytic activity for C3H6 combustion in the temperature range of 250–450 °C. The brownmillerite phase (Ca2Fe2O5) was responsible for the formation of oxygen adspecies (O −2 ) in the surface layer below 450 °C.

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Authors and Affiliations

  1. EcoTopia Science Institute, Nagoya University, Nagoya, 464-8603, Japan

    Daisuke Hirabayashi, Takeshi Yoshikawa, Kazuhiro Mochizuki & Kenzi Suzuki

  2. Department of Chemistry, Daido Institute of Technology, Nagoya, 457-8530, Japan

    Yoichi Sakai

Authors
  1. Daisuke Hirabayashi
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  2. Takeshi Yoshikawa
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  3. Kazuhiro Mochizuki
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  4. Kenzi Suzuki
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  5. Yoichi Sakai
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Correspondence to Daisuke Hirabayashi.

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Hirabayashi, D., Yoshikawa, T., Mochizuki, K. et al. Formation of brownmillerite type calcium ferrite (Ca2Fe2O5) and catalytic properties in propylene combustion. Catal Lett 110, 155–160 (2006). https://doi.org/10.1007/s10562-006-0104-0

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  • DOI: https://doi.org/10.1007/s10562-006-0104-0

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