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Pd/Pt on Ti-containing Mixed Oxides as Dearomatization Catalysts: Physico-chemical Characterization and Activity

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Pd/Pt supported on pure and doped TiO2 (TiO2–WO3 and TiO2–WO3–SiO2) were prepared and characterized by different techniques (XPS, TEM, XRD, H2-TPR and TPD of ammonia). These catalysts were investigated in the hydrogenation of tetralin at 6.0 MPa, checking also their thio-tolerance by feeding increasing amounts of dibenzothiophene (DBT, 300 and 1000 wt ppm). The catalytic activity followed the order: Pd/Pt–TiO2 > Pd/Pt–TiO2–WO3–SiO2 > Pd/Pt–TiO2–WO3, evidencing a negative role of a second oxide inside TiO2. The Pd/Pt–TiO2 catalyst showed high activity regardless of reaction conditions (temperature, contact time, H2/tetralin ratio) together with a good thio-tolerance up to 300 wt ppm of DBT.

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References

  1. B.H. Cooper A. Stanislaus (1994) Catal. Rev. Sci. Eng. 36 75

    Google Scholar 

  2. B.H. Cooper B.B.L. Donnis (1996) Appl. Catal. A137 203

    Google Scholar 

  3. G. Murali Dhar B.N. Srinivas M.S. Rana Manoj Kumar S.K. Maity (2003) Catal. Today 86 45 Occurrence Handle10.1016/S0920-5861(03)00403-6

    Article  Google Scholar 

  4. S. Dzwigaj C. Louis M. Breysse M. Cattenot V. Belliére C. Geantet M. Vrinat P. Blanchard E. Payen S. Inoue H. Kudo Y. Yoshimura (2003) Appl. Catal. B41 181 Occurrence Handle10.1016/S0926-3373(02)00210-2

    Article  Google Scholar 

  5. K. Ito T. Tomino M. Oshima H. Kurokawa K. Sugiyama H. Miura (2003) Appl. Catal. A249 19

    Google Scholar 

  6. E. Lecrenay K. Sakanishi T. Nagamatsu I. Mochida T. Suzuka (1998) Appl. Catal. B18 325 Occurrence Handle10.1016/S0926-3373(98)00054-X

    Article  Google Scholar 

  7. Y. Ji P. Afanasiev M. Vrinat W. Li C. Li (2004) Appl. Catal. A257 157

    Google Scholar 

  8. Y. Saih K. Segawa (2003) Catal. Today 86 61 Occurrence Handle10.1016/S0920-5861(03)00404-8

    Article  Google Scholar 

  9. M.S. Rana S.K. Maity J. Ancheyta G. Murali Dhar T.S.R. Prasada Rao (2003) Appl. Catal. A253 165

    Google Scholar 

  10. E.Y. Kaneko S.H. Pulcinelli V. Teixera da Silva C.V. Santilli (2002) Appl. Catal. A235 71

    Google Scholar 

  11. S.K. Maity J. Ancheyta L. Soberanis F. Alonso M.E. Llanos (2003) Appl. Catal. A244 141

    Google Scholar 

  12. M. Jacquin D.J. Jones J. Rozière S. Albertazzi A. Vaccari M. Lenarda L. Storaro R. Ganzerla (2003) Appl. Catal. A251 131

    Google Scholar 

  13. T. Fujikawa K. Idei T. Ebihara H. Mizuguchi K. Usui (2000) Appl. Catal. A192 253

    Google Scholar 

  14. S. Albertazzi R. Ganzerla C. Gobbi M. Lenarda M. Mandreoli E. Salatelli P. Savini L. Storaro A. Vaccari (2003) J. Mol. Catal. A: Chem. 200 261 Occurrence Handle10.1016/S1381-1169(03)00025-6

    Article  Google Scholar 

  15. M. Jacquin D.J. Jones J. Rozière A. Jiménez López E. Rodríguez-Castellón J.M. Trejo Menayo M. Lenarda L. Storaro A. Vaccari S. Albertazzi (2004) J. Catal. 228 447 Occurrence Handle10.1016/j.jcat.2004.09.017

    Article  Google Scholar 

  16. H. Yasuda Y. Yoshimura (1997) Catal. Lett. 46 43 Occurrence Handle10.1023/A:1019021224505

    Article  Google Scholar 

  17. Shell Report No. 199

  18. S. Albertazzi E. Rodríguez-Castellón M. Livi A. Jiménez-López A. Vaccari (2004) J. Catal. 228 218 Occurrence Handle10.1016/j.jcat.2004.07.023

    Article  Google Scholar 

  19. R.F. Farias Particlede U. Arnold L. Martinéz U. Schuchardt M.J. D.M. Jannini C. Airoldi (2003) J. Phys. Chem. Solids 64 2385 Occurrence Handle10.1016/S0022-3697(03)00276-2

    Article  Google Scholar 

  20. Y. Wang Q. Chen W. Yang Z. Xie W. Xu D. Huang (2003) Appl. Catal. A250 25

    Google Scholar 

  21. E. Pabón J. Retuert R. Quijada A. Zarate (2004) Microp. Mesop. Mater. 67 195 Occurrence Handle10.1016/j.micromeso.2003.10.017

    Article  Google Scholar 

  22. S. Brunauer L.S. Deming W.S. Deming E. Teller (1940) J. Amer. Chem. Soc. 62 1723 Occurrence Handle10.1021/ja01864a025

    Article  Google Scholar 

  23. IUPAC Reporting Physisorption Data for Gas/Solid Systems, Pure Appl. Chem. 57 (1985) 603

  24. A.D. Schmizt G. Bowers C. Song (1996) Catal. Today 31 45 Occurrence Handle10.1016/0920-5861(96)00033-8

    Article  Google Scholar 

  25. B. Pawelec R. Mariscal R.M. Navarro S. Bokhorst Particlevan S. Rojas J.L.G. Fierro (2002) Appl. Catal. A225 223

    Google Scholar 

  26. V.L. Barrio P.L. Arias J.F. Cambra M.B. Güemez B. Pawelec J.L.G. Fierro (2004) Catal. Commun. 5 173 Occurrence Handle10.1016/j.catcom.2004.01.004

    Article  Google Scholar 

  27. A. Spamer T.I. Dube D.J. Moodley C. Schalkwyk Particlevan J.M. Botha (2003) Appl. Catal. A255 153

    Google Scholar 

  28. L. Lietti J.L. Alemany P. Forzatti G. Busca G. Ramis E. Giamello F. Bregani (1996) Catal. Today 29 143 Occurrence Handle10.1016/0920-5861(95)00250-2

    Article  Google Scholar 

  29. M.L. Occelli S. Biz A. Aurox (1999) Appl. Catal. A183 231

    Google Scholar 

  30. S. Klein S. Thorimbert W.F. Maier (1996) J. Catal. 163 476 Occurrence Handle10.1006/jcat.1996.0349

    Article  Google Scholar 

  31. S. Albertazzi I. Baraldini G. Busca E. Finocchio M. Learda L. Storaro A. Talon A. Vaccari (2005) Appl. Clay Sci. 29 224 Occurrence Handle10.1016/j.clay.2005.01.003

    Article  Google Scholar 

  32. M. Skotak D. Lomot Z. Karpinski (2002) Appl. Catal. A229 103

    Google Scholar 

  33. M.A. Vicente J.-F. Lambert (2001) Phys. Chem. Chem. Phys. 3 4843 Occurrence Handle10.1039/b106323p

    Article  Google Scholar 

  34. S. Albertazzi G. Busca E. Finocchio R. Glöckler A. Vaccari (2004) J. Catal. 223 372 Occurrence Handle10.1016/j.jcat.2004.01.024

    Article  Google Scholar 

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Authors and Affiliations

  1. Dipartimento di Chimica Industriale e dei Materiali, Alma Mater Studiorum-Università di Bologna, INSTM-UdR Bologna, Viale del Risorgimento, 4, 40136, Bologna, Italy

    Simone Albertazzi, Christian Barbieri & Angelo Vaccari

  2. Departamento de Química Inorgánica, Cristalografía y Mineralogía, Facultad de Ciencias, Universidad de Málaga, 29071, Málaga, Spain

    Antonia Infantes-Molina, Antonio Jiménez-López, Ramón Moreno-Tost & Enrique Rodríguez-Castellón

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  1. Simone Albertazzi
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  2. Christian Barbieri
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  3. Antonia Infantes-Molina
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  4. Antonio Jiménez-López
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  5. Ramón Moreno-Tost
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  6. Enrique Rodríguez-Castellón
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  7. Angelo Vaccari
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Correspondence to Angelo Vaccari.

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Albertazzi, S., Barbieri, C., Infantes-Molina, A. et al. Pd/Pt on Ti-containing Mixed Oxides as Dearomatization Catalysts: Physico-chemical Characterization and Activity. Catal Lett 104, 29–37 (2005). https://doi.org/10.1007/s10562-005-7432-3

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  • DOI: https://doi.org/10.1007/s10562-005-7432-3

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