Abstract
Molecular beam scattering has been combined with TDS to provide consistent evidence for metal-support interactions (MSI). CO2 adsorbs on the Cu cluster and populated the perimeter of the clusters. The Cu-free areas of the support remain essentially clean. Hence, a synergistic effect such as MSI is present.
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References
T.S. Askgaard J.K. Norskov C.V. Ovesen P. Stoltze (1995) J. Catal. 156 229 Occurrence Handle10.1006/jcat.1995.1250
J.B. Hansen, in Handbook of Heterogeneous Catalysis, eds. G. Ertl, H. Knötzinger and J. Weitkamp, (VCH, 2001)
K. Klier (1982) Adv. Catal. 31 243
B.S. Clausen H. Topsoe (1991) Catal. Today 9 189 Occurrence Handle10.1016/0920-5861(91)85023-2
J. Yoshihara C.T. Campbell (1996) J. Catal. 161 776 Occurrence Handle10.1006/jcat.1996.0240
P.L. Hansen J.B. Wagner S. Helveg J.R. Rostrup-Nielsen B.S. Clausen H. Topsoe (2002) Science 295 2053 Occurrence Handle10.1126/science.1069325 Occurrence Handle11896271
J.D. Grunwaldt A.M. Molenbroek N.Y. Topsoe H. Topsoe B.S. Clausen (2000) J. Catal. 194 452 Occurrence Handle10.1006/jcat.2000.2930
K.D. Jung O.S. Joo S.H. Han (2000) Catal. Lett. 68 49 Occurrence Handle10.1023/A:1019027302428
H. Nakatsuji Z.M. Hu (2000) Intern. J. Quantum Chem. 77 341 Occurrence Handle10.1002/(SICI)1097-461X(2000)77:1<341::AID-QUA33>3.0.CO;2-T
I. Nakamura H. Nakano T. Fujitani T. Uchijima J. Nakamura (1998) Surf. Sci. 402–404 92 Occurrence Handle10.1016/S0039-6028(97)00910-2
K.C. Waugh (1999) Catal Lett. 58 163 Occurrence Handle10.1023/A:1019025816831
S.A. French (2001) Angew. Chem. 113 4569 Occurrence Handle10.1002/1521-3757(20011203)113:23<4569::AID-ANGE4569>3.0.CO;2-F
D.W. Goodman (2005) J. Catal. Lett. 99 1 Occurrence Handle10.1007/s10562-004-0768-2
R. Meyer M. Baumer S.K. Shaikhutdinov H.J. Freund (2003) Surf. Sci. 546 L813 Occurrence Handle10.1016/j.susc.2003.09.025
Q. Fu T. Wagner S. Olliges H.D. Carstanjen (2005) J. Phys. Chem. 109 944
G.A. Somorjai
J.C. Frost (1988) Nature 334 577 Occurrence Handle10.1038/334577a0
S.V. Didziulis K.D. Butcher S.L. Cohen E.I. Solomon (1989) J. Am. Chem. Soc. 111 7110 Occurrence Handle10.1021/ja00200a033
G. Thornton S. Crook Z. Chang (1998) Surf. Sci. 415 122 Occurrence Handle10.1016/S0039-6028(98)00518-4
J. Yoshihara C.T. Campbell (1998) Surf. Sci. 407 256 Occurrence Handle10.1016/S0039-6028(98)00201-5
B. Meyer D. Marx (2004) Phys. Rev. B 69 235420 Occurrence Handle10.1103/PhysRevB.69.235420
G. Kresse O. Dulub U. Diebold (2003) Phys. Rev. B 68 245409 Occurrence Handle10.1103/PhysRevB.68.245409
J. Yoshihara J.M. Campbell C.T. Campbell (1998) Surf. Sci. 406 235 Occurrence Handle10.1016/S0039-6028(98)00117-4
J. Wang and E. Johnson, U. Burghaus, Chem. Phys. Lett. (in press)
J. Wang B. Hokkanen U. Burghaus (2005) Surf. Sci. 577 158 Occurrence Handle10.1016/j.susc.2004.12.030
K.H. Ernst D. Schlatterbeck K. Christmann (1999) Phys. Chem. Chem. Phys. 1 4105 Occurrence Handle10.1039/a904169i
J. Wang U. Burghaus (2005) J. Chem. Phys. 122 044705-11
D.W. Goodmann (1996) J. Chem. Phys. 100 13090 Occurrence Handle10.1021/jp953755e
U. Burghaus J. Ding W.H. Weinberg (1998) Surf. Sci. 396 273 Occurrence Handle10.1016/S0039-6028(97)00676-6
C. Xu B.E. Koel M.T. Paffett (1994) Langmuir 10 166 Occurrence Handle10.1021/la00013a025
D.A. King M.G. Wells (1972) Surf. Sci. 29 454 Occurrence Handle10.1016/0039-6028(72)90232-4
F. Rumpf H. Poppa M. Boudard (1988) Langmuir 4 722 Occurrence Handle10.1021/la00081a038
J. Stephan U. Burghaus (2002) Surf. Sci. 507–510 736 Occurrence Handle10.1016/S0039-6028(02)01345-6
H.B. Nielsen U. Burghaus G. Broström E. Matthias (1990) Surf. Sci. 234 L271 Occurrence Handle10.1016/0039-6028(90)90552-J
S.J. Tauster S.C. Fung R.T.K. Baker J.A. Horsley (1981) Science 211 1121
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Wang, J., Funk, S. & Burghaus, U. Indications for Metal-support Interactions: The Case of CO2Adsorption on Cu/ZnO(0001). Catal Lett 103, 219–223 (2005). https://doi.org/10.1007/s10562-005-7157-3
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DOI: https://doi.org/10.1007/s10562-005-7157-3