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Hydrocarboxylation of Styrene in Aqueous Media with Pd-guanidinumphosphine Systems

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Hydrosoluble palladium complexes with guanidinumphosphine ligands are active catalyst precursors for the hydrocarboxylation of styrene forming the corresponding carboxylic acids using water as a solvent. The aryl guanidinum derivative is much more stable than the alkyl derivative studied and provided high selectivity in the acids with conversions up to 96%.

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Authors and Affiliations

  1. Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, c/Marcel·lí Domingo, s/n, 43007, Tarragona, Spain

    Ali Aghmiz, Anna M. Masdeu-Bultó & F. P. Schmidtchen

  2. Technische Universität München, D-85747, Garching, Germany

    Marta Giménez-Pedrós

Authors
  1. Ali Aghmiz
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  2. Marta Giménez-Pedrós
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  3. Anna M. Masdeu-Bultó
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  4. F. P. Schmidtchen
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Correspondence to Anna M. Masdeu-Bultó.

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Aghmiz, A., Giménez-Pedrós, M., Masdeu-Bultó, A.M. et al. Hydrocarboxylation of Styrene in Aqueous Media with Pd-guanidinumphosphine Systems. Catal Lett 103, 191–193 (2005). https://doi.org/10.1007/s10562-005-7153-7

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  • DOI: https://doi.org/10.1007/s10562-005-7153-7

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