Skip to main content
SpringerLink
Log in

Gold supported CeO2/Al2O3 catalysts for CO oxidation: influence of the ceria phase

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

A series of low loading gold supported ceria/alumina catalysts have been prepared by the deposition–precipitation method, varying the pH of the synthesis. The catalysts were characterised by means of XRD, TEM, SBET, XRF and UV–Vis techniques, and their catalytic activity towards CO oxidation in the absence and in presence of water in the stream, were tested. It has been found that in this low loading gold catalysts, where the metallic particles are far away one from another and the oxygen transportation is not the limiting step of the reaction, the electronic properties of the ceria phase and the structure of the metal-support perimeter more than the diameter of the gold nanoparticles is the determinant factor in the catalytic performances of the solid.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G.C. Bond D.T. Thompson (1999) Catal. Rev.-Sci. Eng. 41 319 Occurrence Handle10.1081/CR-100101171

    Article  Google Scholar 

  2. G.J. Hutchings (2004) Gold. Bullet. 37 3

    Google Scholar 

  3. M. Haruta (1997) Catal. Today 36 153 Occurrence Handle10.1016/S0920-5861(96)00208-8

    Article  Google Scholar 

  4. V. Idakiev T. Tabakova Z.-Y. Yuan B. Su (2004) Appl. Catal. A 270 135 Occurrence Handle10.1016/j.apcata.2004.04.030

    Article  Google Scholar 

  5. Y. Tai J. Murakami K. Tajiri F. Ohashi M. Daté S. Tsubota (2004) Appl. Catal. A 268 183 Occurrence Handle10.1016/j.apcata.2004.03.039

    Article  Google Scholar 

  6. D. Andreeva R. Nedyalkova L. Ilieva M.V. Abrashev (2004) Appl. Catal. B 52 157 Occurrence Handle10.1016/j.apcatb.2004.03.019

    Article  Google Scholar 

  7. L. Guczi D. Horvath Z. Paszti G. Peto (2002) Catal. Today 72 101 Occurrence Handle10.1016/S0920-5861(01)00483-7

    Article  Google Scholar 

  8. M. Olea Y. Iwasawa (2004) Appl. Catal. A 275 35

    Google Scholar 

  9. S. Ivanova C. Petit V. Pitchon (2004) Appl. Catal. A 267 191 Occurrence Handle10.1016/j.apcata.2004.03.004

    Article  Google Scholar 

  10. M.A. Centeno I. Carrizosa J.A. Odriozola (2003) Appl. Catal. A 246 365 Occurrence Handle10.1016/S0926-860X(03)00058-9

    Article  Google Scholar 

  11. M.M. Schubert S. Hackemberg A.C. Veen Particlevan M. Muhler V. Plzak R.J. Behm (2001) J. Catal. 197 113 Occurrence Handle10.1006/jcat.2000.3069

    Article  Google Scholar 

  12. A. Martinez-Arias M. Fernandez-Garcia L.N. Salamanca R.X. Valenzuela J.C. Conesa J. Soria (2000) J. Phys. Chem. B 104 4038 Occurrence Handle10.1021/jp992796y

    Article  Google Scholar 

  13. M.A. Centeno M. Paulis M. Montes J.A. Odriozola (2002) Appl. Catal. A 234 65 Occurrence Handle10.1016/S0926-860X(02)00214-4

    Article  Google Scholar 

  14. M.A. Centeno, M.I. Domínguez, I. Carrizosa, J.A. Odriozola, Proceedings of the XVIII Iberoamerican Symposium on Catalysis (2002), p. 2640

  15. S. Tsubota, D.A. Cunningham, Y. Bando, M. Haruta, in: G.␣Poncelet, P. Grange and P.A. Jacobs (eds)., Preparation of Catalysts VI, Elsevier, Amsterdam, 1995, p. 227.

  16. M.I. Zaki G.A.M. Hussein S.A.A. Manssur H.M. Ismael G.A.H. Mekhemer (1997) Colloids and Surfaces A 127 47 Occurrence Handle10.1016/S0927-7757(96)03943-X

    Article  Google Scholar 

  17. A. Bensalem J.C. Muller F. Bozon-Verduraz (1992) J. Chem. Soc. Faraday Trans. 88 153 Occurrence Handle10.1039/ft9928800153

    Article  Google Scholar 

  18. J.A. Navio M.C. Hidalgo G. Colón S.G. Botta M.I. Litter (2001) Langmuir 17 202 Occurrence Handle10.1021/la000897d

    Article  Google Scholar 

  19. G.R. Rao H.R. Sahu (2001) Proc. Indian. Acad. Sci. (Chem. Sci.) 113 651

    Google Scholar 

  20. S.P. Tandom J.P. Gupta (1970) Phys. Stat. Sol. 38 363

    Google Scholar 

  21. R.S. Weber (1995) J. Catal. 151 470

    Google Scholar 

  22. D.G. Barton M. Shtein R.D. Wilson S.L. Soled E. Iglesia (1999) J. Phys. Chem. B 103 630 Occurrence Handle10.1021/jp983555d

    Article  Google Scholar 

  23. N.V. Skorodumova R. Ahuja S.I. Simak I.A. Abrikosov B. Johansson B.I. Lundqvist (2001) Phys. Review B 64 115108 Occurrence Handle10.1103/PhysRevB.64.115108

    Article  Google Scholar 

  24. M.A. Centeno M.J. Capitán P. Malet I. Carrizosa J.A. Odriozola (1994) J. Catal. 148 399

    Google Scholar 

  25. K.B. Sundaram P. Wahid (1990) Phys. Rev. B 161 163

    Google Scholar 

  26. P. Mulvaey (1996) Langmuir 12 788 Occurrence Handle1:CAS:528:DyaK28XjvVKqsQ%3D%3D

    CAS  Google Scholar 

  27. P. Bera M.S. Hedge (2002) Catal. Lett. 79 107

    Google Scholar 

  28. J. Soria J.M. Coronado J.C. Conesa (1996) J. Chem. Soc. Faraday Trans 92 1619

    Google Scholar 

  29. C. Morterra V. Bolis G. Magnacca (1996) J. Chem. Soc. Faraday Trans. 92 1991

    Google Scholar 

  30. M. Haruta M. Date (2001) Appl. Catal. A 222 427

    Google Scholar 

  31. T. Tabakova F. Bocuzzi M. Manzini D. Andreeva (2003) Appl. Catal. A 252 385

    Google Scholar 

  32. G.C. Bond D.T. Thompson (2000) Gold Bull. 33 41

    Google Scholar 

  33. Q. Fu S. Kudriavtseva H. Satsburg M. Flytzani-Stephanopoulus (2003) Chem. Eng. J. 93 41

    Google Scholar 

  34. C. Padeste N. Cant D. Trimm (1993) Catal. Lett. 18 305

    Google Scholar 

  35. S. Deki Y. Aoi H. Yanagimoto K. Ishii K. Akamatsu M. Mizuhata A. Kajinami (1996) J. Mater. Chem. 6 1879

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla, Avda Americo Vespuccio s/n, 41092, Sevilla, Spain

    Miguel Ángel Centeno, Cristina Portales, Ignacio Carrizosa & José Antonio Odriozola

Authors
  1. Miguel Ángel Centeno
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Cristina Portales
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ignacio Carrizosa
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. José Antonio Odriozola
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Miguel Ángel Centeno.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Centeno, M.Á., Portales, C., Carrizosa, I. et al. Gold supported CeO2/Al2O3 catalysts for CO oxidation: influence of the ceria phase. Catal Lett 102, 289–297 (2005). https://doi.org/10.1007/s10562-005-5871-5

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-005-5871-5

Keywords

Search

Navigation