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A pronounced catalytic activity of heteropoly compounds supported on dealuminated USY for liquid-phase esterification of acetic acid with n-butanol

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Abstract

12-Phosphotungstic acid and its cesium salts supported on a dealuminated ultra-stable Y zeolite were prepared, and showed the high catalytic activity in the liquid-phase esterification of acetic acid with n-butanol. The supported Cs2.5H0.5PW12O40 catalyst gave a high conversion of n-butanol of 94.6% and a selectivity for n-butyl acetate of 100%, accompanying the high water-tolerance and catalytic reusability without regeneration.

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Authors and Affiliations

  1. Key Laboratory of Materials-Oriented Chemical Engineering of Jiangsu Province, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing, 210009, P.R. China

    Fu-Min Zhang, Jun Wang, Chao-Shu Yuan & Xiao-Qian Ren

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  1. Fu-Min Zhang
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  2. Jun Wang
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  3. Chao-Shu Yuan
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  4. Xiao-Qian Ren
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Correspondence to Jun Wang.

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Zhang, FM., Wang, J., Yuan, CS. et al. A pronounced catalytic activity of heteropoly compounds supported on dealuminated USY for liquid-phase esterification of acetic acid with n-butanol. Catal Lett 102, 171–174 (2005). https://doi.org/10.1007/s10562-005-5851-9

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  • DOI: https://doi.org/10.1007/s10562-005-5851-9

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