It is shown that in the mineral transformer oil oxidation process the fluorescence spectrum of the oil shifts to the long-wave region. This phenomenon lies at the foundation of the method of determination of the degree of electroinsulating oil oxidation in real time. The oxidation state is determined by measuring the diagnostic parameter, i.e., the oxidation index that characterizes the magnitude of shift of the fluorescence spectrum of the oil upon its oxidation. The oxidation index is defined as the ratio of the fluorescence intensity measured in the longer-wave spectral range to the intensity measured in the shorter-wave spectral range. The results of measurement of the transformer oil oxidation degree by the fluorescence method vis-à-vis other measurement methods, such as titration and IR spectroscopy, are presented. The proposed method can be used to determine the increase in oil oxidation rate at the earlier stage. The device for implementing the developed method can be a portable one or can be installed in the oil-filled system of the equipment.
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REFERENCES
V. V. Buzaev, Yu. M. Sapozhnikov, Yu. Dementiev, et al., Energetik, No. 11, 9-12 (2004).
J. A. Palmer, X. Wang, A. Mander, et al., in: Proceedings of the IEEE International Symposium on Electrical Insulation, Anaheim, CA, USA, 2–5 April 2000, p. 460–464.
B. A. Alekseev, ELEKTRO. Elektrotekhnika, elektroenergetika, elektrotekhnicheskaya promyshlennost’, No. 2, 10-15 (2002).
S. Deepa, R. Sarathi, and A. K. Mishra, Talanta, 70, 811–817 (2006).
D. M. Valiullina and V. K. Kozlov, Problemy Energetiki, No. 9-10, 169-171, (2003).
A. Sierota and J. Rungis, Electrical Insulation Magazine IEEE, 11, No. 1, 8–20 (1995).
B. Pradier, C. Largeau, S. Derenne, et al., Organic Geochemistry, 16, No. 1–3, 451–460 (1990).
K. Najdenkoski, G. Rafajlovski, V. Dimcev, et al., in: Proceedings of the IEEE on Power Engineering Society General Meeting, Tampa Florida, USA, 24–28 June 2007, p. 1–5.
P. Parvin, S. Z. Shoursheini, F. Khalilinejad, et al., Optics and Lasers in Engineering, 50, No. 11, p. 1672–1676 (2012).
US Patent 7136155.
J. F. Fantasia and H. C. Ingrao, in: Proceedings of the 9th International Symposium on Remote Sensing of the Environment, Ann Arbor, Michigan, 15–19 April 1974, p. 1711–1745.
P. Camagni, Applied Optics, 30, No. 1, p. 26–35 ((1991).
US Patent 6633043.
E. L. Wehry, Fluorescence: Theory, Instrumentation and Practice, ed. G. G. Guilbault, New York, Dekker, p. 37–132 (1967).
L. V. Markova, N. K. Myshkin, C. V. Ossia, et al., Tribology in Industry, 29, No. 1–2, p. 33–36 (2007).
C. V. Ossia, H. Kong, L. V. Markova, et al., Tribology International, No. 41, p. 103–110 (2008).
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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 2, pp. 46 – 50, March – April, 2016.
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Markova, L.V., Myshkin, N.K. & Makarenko, V.M. Fluorescence Method for Quick Transformer Oil Monitoring. Chem Technol Fuels Oils 52, 194–202 (2016). https://doi.org/10.1007/s10553-016-0690-5
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DOI: https://doi.org/10.1007/s10553-016-0690-5