Abstract
We evaluated nitrogen (N) export for various catchments in the San Pedro River watershed of South-central Chile (39°20′ to 40°12′S) during the dry season (February to March). We measured concentrations and export of the various N species at 16 points from the Andean headwaters to the lowland portion of the watershed: eight main nested points along the main watershed and eight secondary points on tributaries. We expected that, given a downstream increase in pastureland and decrease in native pristine forest cover, inorganic forms of N (DIN) would increase downstream, while conversely, dissolved organic nitrogen (DON) would decrease compared with concentrations in the forested headwaters. Nitrogen concentrations did not show statistically significant differences among the nested catchments. However, there were statistically significant differences in N concentrations associated with land cover among the tributaries. The results suggest that in the presence of base flow, natural landscape properties (barren land, lakes and rivers), explained most of the spatial variation in the N exports, while anthropogenic disturbance was not detectable. There was a negative relationship between DIN export and the coverage of lakes and rivers, suggesting that lakes might be acting as N traps. On the other hand, DIN, DON and total N exports were positively associated to barren land. Total nitrogen export during this 60-day dry season was less than 20 kg km−2 and the annual export was not larger than 100 kg km−2. This study documents the as yet pristine conditions of rivers in southern Chile.
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Acknowledgments
We would like to thank the Scientific Millennium Initiative (project P01-057-F and P04-065-F) for funding this research; Gene Likens and Myrna Hall for their comments to this investigation; Eduardo Neira for his support in the preparation of the images and Brooke Penaluna for her support in the translation. We also thank the valuable comments from two anonymous reviewers.
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Little, C., Soto, D., Lara, A. et al. Nitrogen exports at multiple-scales in a southern Chilean watershed (Patagonian Lakes district). Biogeochemistry 87, 297–309 (2008). https://doi.org/10.1007/s10533-008-9185-8
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DOI: https://doi.org/10.1007/s10533-008-9185-8