Skip to main content
Log in

Ultraphosphate glasses for immobilization of liquid plutonium-containing wastes

  • Published:
Atomic Energy Aims and scope

Abstract

Ultraphosphate glass is proposed for immobilization, taking account of the composition of the plutonium-containing wastes at the Mining-Chemical conglomerate. Some parameters of the process of immobilizing in ultraphosphate glass model wastes with plutonium content up to 150 mg/liter are investigated. A preliminary study is made of the degree of inclusion of plutonium dioxide, the chemical stability of the ultraphosphate glass obtained, and the distribution of plutonium in it. It is shown that almost 2 times more plutonium dioxide is included in ultraphosphate glass than in phosphate glass. With respect to the main physicochemical parameters, specifically, component leachability, ultraphosphate glass can be regarded as promising for immobilizing liquid plutonium-containing wastes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. A. Vashman and A. S. Polyakov (eds.), Phosphate Glasses with Radioactive Wastes, TsNIIatominform, Moscow (1997), pp. 48–65.

    Google Scholar 

  2. N. E. Alekseev, V. N. Gapontsev, M. E. Zhabotinskii, et al., Laser Phosphate Glasses, Nauka, Moscow (1980).

    Google Scholar 

  3. J. Gill and S. Riaz, “Some investigations concerning the structure of ultraphosphates,” J. Chem. Soc., Ser. A, No. 5, 843–849 (1969).

  4. Radioactive Wastes. Laboratory Measurements of the Chemical Stability of Solidified Radioactive Wastes by Prolonged Leaching, GOST 29114-91, Standarty, Moscow (1991).

Download references

Author information

Authors and Affiliations

Authors

Additional information

__________

Translated from Atomnaya Énergiya, Vol. 100, No. 5, pp. 368–372, May, 2006.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Borisov, G.B., Nazarov, A.V., Poluéktov, P.P. et al. Ultraphosphate glasses for immobilization of liquid plutonium-containing wastes. At Energy 100, 346–349 (2006). https://doi.org/10.1007/s10512-006-0092-6

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10512-006-0092-6

Keywords

Navigation