Abstract
The influence of NOx and SO2 contaminants on CO2 capture by adsorption was investigated using a carbon fiber textile as an adsorbent. The study was made in a dynamic system, studying the contaminant alone and in binary or ternary mixtures. The results at short times showed that the CO2 capacity and kinetics were not impacted by the presence of NOx in the entrance gas whereas the NOx capacity was slightly impacted by the presence of CO2. In the presence of SO2, the CO2 capacity loss reached 10%. Moreover, with NOx and SO2 accumulation at the surface of the textile, the loss of CO2 capacity can reach 25% and SO2 adsorption is favored to the detriment of NO. For CO2 capture processes by adsorption de-SOx pretreatment is recommended.
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Atkinson, J.D., Zhang, Z.Q., Yan, Z.F., Rood, M.J.: Evolution and impact of acidic oxygen functional groups on activated carbon fiber cloth during NO oxidation. Carbon 54, 444–453 (2013). https://doi.org/10.1016/j.carbon.2012.11.060
Choi, S., Drese, J.H., Jones, C.W.: Adsorbent materials for carbon dioxide capture from large anthropogenic point sources. Chemsuschem 2(9), 796–854 (2009). https://doi.org/10.1002/cssc.200900036
D’alessandro, D., Smit, B., Long, J., : Carbon dioxide capture: prospects for new materials. Angew. Chem. Int. 49, 6058–6082 (2010). https://doi.org/10.1002/anie.201000431
Guo, Y.Y., Li, Y.R., Zhu, T.Y., Ye, M.: Investigation of SO2 and NO adsorption species on activated carbon and the mechanism of NO promotion effect on SO2. Fuel 143, 536–542 (2015). https://doi.org/10.1016/j.fuel.2014.11.084
Hedin, N., Andersson, L., Bergström, L., Yan, J.: Adsorbents for the post-combustion capture of CO2 using rapid temperature swing or vacuum swing adsorption. Appl. Energy 104, 418–433 (2013). https://doi.org/10.1016/j.apenergy.2012.11.034
Hornbostel, M.D., Bao, J., Krishnan, G., Nagar, A., Jayaweera, I., Kobayashi, T., Sanjurjo, A., Sweeney, J., Carruthers, D., Petruska, M.A., Dubois, L.: Characteristics of an advanced carbon sorbent for CO2 capture. Carbon 56, 77–85 (2013). https://doi.org/10.1016/j.carbon.2012.12.082
Klose, W., Rincon, S.: Adsorption and reaction of NO on activated carbon in the presence of oxygen and water vapour. Fuel 86(1–2), 203–209 (2007). https://doi.org/10.1016/j.fuel.2006.06.017
Lastoskie, C., Gubbins, K.E., Quirke, N.: Pore size distribution analysis of microporous carbons: a density functional theory approach. J. Phys. Chem. 97(18), 4786–4796 (1993). https://doi.org/10.1021/j100120a035
Li, B., Duan, Y., Luebke, D., Morreale, B.: Advances in CO2 capture technology: a patent review. Appl. Energy 102, 1439–1447 (2013). https://doi.org/10.1016/j.apenergy.2012.09.009
Lizzio, A.A., Debarr, J.A.: Mechanism of SO2 removal by carbon. Energy Fuels 11(2), 284–291 (1997). https://doi.org/10.1021/ef960197+
Luo, L., Guo, Y.Y., Zhu, T.Y., Zheng, Y.: Adsorption species distribution and multicomponent adsorption mechanism of SO2, NO, and CO2 on commercial adsorbents. Energy Fuels 31(10), 11026–11033 (2017). https://doi.org/10.1021/acs.energyfuels.7b01422
Samanta, A., Zhao, A., Shimizu, G., Sarkar, P., Gupta, R.: Post-combustion CO2 capture using solid sorbents: a review. Ind. Eng. Chem. Res. 51, 1438–1463 (2012). https://doi.org/10.1021/ie200686q
Sayari, A., Belmabkhout, Y., Serna-Guerrero, R.: Flue gas treatment via CO2 adsorption. Chem. Eng. J. 171(3), 760–774 (2011). https://doi.org/10.1016/j.cej.2011.02.007
Sjostrom, S., Krutka, H.: Evaluation of solid sorbents as a retrofit technology for CO2 capture. Fuel 89, 1298–1306 (2010). https://doi.org/10.1016/j.fuel.2009.11.019
Sjostrom, S., Krutka, H., Starns, T., Campbel, T.: Pilot test results of post-combustion CO2 capture using solid sorbents. Energy Procedia 4, 1584–2159 (2011). https://doi.org/10.1016/j.egypro.2011.02.028
Sreenivasulu, B., Gayatri, D.V., Sreedhar, I., Raghavan, K.V.: A journey into the process and engineering aspects of carbon capture technologies. Renew. Sustain. Energy Rev. 41, 1324–1350 (2015). https://doi.org/10.1016/j.rser.2014.09.029
Thiruvenkatachari, R., Su, S., Yu, X.X., Jin, Y.G.: A site trial demonstration of CO2 capture from real flue gas by novel carbon fibre composite monolith adsorbents. Int. J. Greenh. Gas Control 42, 415–423 (2015). https://doi.org/10.1016/j.ijggc.2015.08.018
Thommes, M., Kaneko, K., Neimark, A.V., Olivier, J.P., Rodriguez-Reinoso, F., Rouquerol, J., Sing, K.S.W.: Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl. Chem. 87(9–10), 1051–1069 (2015)
Wang, J., Huang, L., Yang, R., Zhang, Z., Wu, J., Gao, Y., Wang, Q., O'Hare, D., Zhong, Z.: Recent advances in solid sorbents for CO2 capture and new development trends. Energy Environ. Sci. 7, 3478–3518 (2014). https://doi.org/10.1039/C4EE01647E
Yi, H.H., Wang, Z.X., Liu, H.Y., Tang, X.L., Ma, D., Zhao, S.Z., Zhang, B.W., Gao, F.Y., Zuo, Y.R.: Adsorption of SO2, NO, and CO2 on activated carbons: equilibrium and thermodynamics. J. Chem. Eng. Data 59(5), 1556–1563 (2014). https://doi.org/10.1021/je4011135
Yu, C.-H., Huang, C.-H., Tan, C.-S.: A review of CO2 capture by absorption and adsorption. Aerosol. Air Q. Res. 12(5), 745–769 (2012). https://doi.org/10.4209/aaqr.2012.05.0132
Zhang, W.J., Rabiei, S., Bagreev, A., Zhuang, M.S., Rasouli, E.: Study of NO adsorption on activated carbons. Appl. Catal. B 83(1–2), 63–71 (2008). https://doi.org/10.1016/j.apcatb.2008.02.003
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Boumghar, S., Bedel, S., Sigot, L. et al. Adsorption of CO2 in presence of NOx and SOx on activated carbon textile for CO2 capture in post-combustion conditions. Adsorption 26, 1173–1181 (2020). https://doi.org/10.1007/s10450-020-00207-6
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DOI: https://doi.org/10.1007/s10450-020-00207-6