Abstract
Carbon dioxide and methane are major compounds involved in global warming. The process of CO2 and CH4 molecules absorption by water clusters was investigated by the molecular dynamics method. The frequency spectra of dielectric permittivity for systems consisting of (H2O) n , (CO2) i (H2O)10 and (CH4) i (H2O)10 clusters mixed in various proportions were determined. The IR radiation absorption spectra of these systems were calculated and compared. Also, the radiating power of these systems was established. The capture of greenhouse gases’ molecules by ultra disperse water media reduces the ability of the media to absorb the Earth’s radiation, i.e., it reduces the greenhouse effect.
Similar content being viewed by others
References
Angell CA, Rodgers V (1984) Near infrared spectra and the disrupted network model of normal and supercooled water. J Chem Phys 80:6245–6252
Bosma WB, Fried LE, Mukamel S (1993) Simulation of the intermolecular vibrational spectra of liquid water and water clusters. J Chem Phys 98:4413–4421
Bresme F (2001) Equilibrium and nonequilibrium molecular-dynamics of the central force model of water. J Chem Phys 115:7564–7574
Dang LX, Chang T-M (1997) Molecular dynamics study of water clusters, liquid, and liquid–vapor interface of water with many-body potentials. J Chem Phys 106:8149–8159
Galashev AY, Chukanov VN (2004) Computer simulation of the stability of water clusters containing nitrogen oxide molecules. Colloid J 66:523–530
Goggin PL, Carr C (1986) Far infrared spectroscopy and aqueous solutions. In: Neilson GW, Enderby JE (eds) Water and aqueous solutions. Adam Hilger, Bristol 37:149–161
Hertzberg G (1949) Vibrational and rotary spectra of polyatomic molecules. Foreign Literature, Moscow
Kozintzev VI, Belov ML, Gorodnichev VA, Fedotov UV (2003) Laser optical acoustic analysis of multicomponent gas mixtures. MSTU named N. E. Bauman, Moscow
Landau LD, Lifshitz EM, Pitaevski LP (1984) Electrodynamics of continuous media. Pergamon, Oxford
Neumann M (1985) The dielectric constant of water. Computer simulations with the MCY potential. J Chem Phys 82:5663–5672
Neumann M (1986) Dielectric relaxation in water. Computer simulations with the TIP4P potential. J Chem Phys 85:1567–1679
Peixoto JP, Oort AH (1992) Physics of climate. Springer, Berlin
Prokhorov AM (ed) (1988) Physical encyclopedia 1. Sovetskaya Encyclopediya, Moscow
Spackman MA (1986) A simple quantitative model of hydrogen bonding. J Chem Phys 85:6587–6601
Stern HA, Berne BJ (2001) Quantum effects in liquid water: path-integral simulations of a flexible and polarizable ab initio model. J Chem Phys 115:7622–7628
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Galashev, A.Y. Greenhouse effect of clusterization of CO2 and CH4 with atmospheric moisture. Environ Chem Lett 9, 37–41 (2011). https://doi.org/10.1007/s10311-009-0243-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10311-009-0243-9