Abstract
Due to the important role of oil source in our life, the separation of water-in-oil emulsion is urgent and necessary. Membrane seperation technology has been an efficient and widely used method in separating oil-water separation. Herein, we report a versatile approach to fabricate surface carbonized membranes with self-standing property from biomass-derived precursor by synergistic charring of phytic acid, arginine and filter paper. The obtained membrane exhibited superhydrophobicity in oil, excellent fouling resistance, and self-supporting ability. The membrane can be cycle-used at least 12 times with high permeation flux (up to 1380 L·m−2·h−1) and separation efficiency (up to 99.4%).
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Wang, B.; Liang, W. X.; Guo, Z. G.; Liu, W. M. Biomimetic super-lyophobic and super-lyophilic materials applied for oil/water separation: a new strategy beyond nature. Chem. Soc. Rev. 2015, 44, 336–361.
Zeng, X. J.; Qian, L.; Yuan, X. X.; Zhou, C. L.; Li, Z. W.; Cheng, J.; Xu, S. P.; Wang, S. F.; Pi, P. H.; Wen, X. F. Inspired by stenocara beetles: from water collection to high-efficiency water-in-oil emulsion separation. ACS Nano 2017, 11, 760–769.
Masato, K.; Masahiro, G. Demulsification of water-in-oil emulsions by permeation through Shirasu-porous-glass (SPG) membranes. J. Membr. Sci. 2008, 322, 196–203.
Lu, S.; Wang, Z. X.; Zhang, Y. L.; Jiang, Z. X.; Liu, Y. Y. A facile strategy to enhance PVDF ultrafiltration membrane performance via self-polymerized polydopamine followed by hydrolysis of ammonium fluotitanate. J. Membr. Sci. 2014, 461, 10–21.
Wang, Y.; Hu, T. T.; Han, X. L.; Wang, Y. Q.; Li, J. D. Fabrication of Cu(OH)2 nanowires blended poly(vinylidene fluoride) ultrafiltration membranes for oil-water separation. Chinese J. Polym. Sci. 2018, 36, 612–619.
Li, X. Y.; Hu, D.; Huang, K.; Yang, C. F. Hierarchical rough surfaces formed by LBL selfassembly for oil-water separation. J. Mater. Chem. A 2014, 2, 11830–11838.
Zhang, W. F.; Liu, N.; Cao, Y. Z.; Lin, X.; Liu, Y. N.; Feng, L. Superwetting porous materials for wastewater treatment: from immiscible oil/water mixture to emulsion separation. Adv. Mater. Interfaces 2017, 4, 1700029.
Bader, S. A.; Ong, C. S. Recent developments of carbon based nanomaterials and membranes for oily wastewater treatment. RSC Adv. 2017, 7, 20981–20994.
Feng, S. Z.; Luo, W. X.; Wang, L. X.; Zhang, S.; Guo, N. N.; Xu, M. J.; Zhao, Z. B.; Jia, D. Z.; Wang, X. C.; Jia, L. X. Preparation and property of extremely stable superhydrophobic carbon fibers with core-shell structure. Carbon 2019, 150, 284–291.
Ma, J. X.; Ping, D.; Dong, X. F. Recent developments of graphene oxide-based membranes: a review. Membranes 2017, 7, 52–80.
Yue, X. J.; Zhang, T.; Yang, D. Y.; Qiu, F. X.; Li, Z. D. Hybrid aerogels derived from banana peel and waste paper for efficient oil absorption and emulsion separation. J. Clean. Prod. 2018, 199, 411–419.
Gong, J.; Chen, X. C.; Tang, T. Recent progress in controlled carbonization of (waste) polymers. Prog. Polym. Sci. 2019, 94, 1–32.
Chen, L.; Wang, Y. Z. A review on flame retardant technology in China. Part I: development of flame retardants. Polym. Adv. Technol. 2010, 21, 1–26.
Shi, X. H.; Chen, L.; Liu, B. W.; Long, J. W.; Xu, Y. J.; Wang, Y. Z. Carbon fibers decorated by polyelectrolyte complexes toward their epoxy resin composites with high fire safety. Chinese J. Polym. Sci. 2018, 36, 1375–1384.
Viola, H.; Eva, S.; Nadezda, S. Characterization of cellulosic fibers by FTIR spectroscopy for their further implementation to building materials. Am. J. Anal. Chem. 2018, 9, 303–310.
Zhang, T.; Yan, H. Q.; Shen, L.; Fang, Z. P.; Zhang, X. M.; Wang, J. J.; Zhang, B. Y. Chitosan/phytic acid polyelectrolyte complex: a green and renewable intumescent flame retardant system for ethylene-vinyl acetate copolymer. Ind. Eng. Chem. Res. 2014, 53, 19199–19207.
Valappil, S. P.; Ready, D.; Neel, E. A. A.; Pickup, D. M.; Chrzanowski, W.; O’Dell, L. A.; Newport, R. J.; Smith, M. E.; Wilson, M.; Knowles, J. C. Antimicrobial gallium-doped phosphate-based glasses. Adv. Funct. Mater. 2008, 18, 732–741.
Xu, F.; Yu, J.; Tesso, T.; Dowell, F.; Wang, D. Qualitative and quantitative analysis of lignocellulosic biomass using infrared techniques: a mini-review. Appl. Energy 2013, 104, 801–809.
Fackler, K.; Stevanic, J. S.; Ters, T.; Hinterstoisser, B.; Schwanninger, M.; Salmén, L. FTIR imaging spectroscopy to localise and characterise simultaneous and selective white-rot decay within sprude woodcell. Holzforschung 2011, 65, 411–420.
Gao, Y. Y.; Deng, C.; Du, Y. Y.; Huang, S. C.; Wang, Y. Z. A novel bio-based flame retardant for polypropylene from phytic acid. Polym. Degrad. Stab. 2019, 298–308.
Du, S. L.; Lin, X. B.; Jian, R. K.; Deng, C.; Wang, Y. Z. Flame-retardant wrapped ramie fibers towards suppressing “candlewick effect” of polypropylene/ramie fiber composites. Chinese J. Polym. Sci. 2015, 33, 84–94.
Laufer, G.; Kirkland, C.; Cains, A. A.; Grunlan, J. C. Clay-chitosan nanobrick walls: completely renewable gas barrier and flame-retardant nanocoatings. ACS Appl. Mater. Interfaces 2012, 4, 1643–1649.
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This work was financially supported by the National Natural Science Foundation of China (Nos. 21875147 and 51991351) and the Fundamental Research Funds for the Central Universities.
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Cao, JYQ., Chen, SC., Zhang, J. et al. A Self-supporting, Surface Carbonized Filter Paper Membrane for Efficient Water-in-Oil Emulsion Separation. Chin J Polym Sci 39, 181–188 (2021). https://doi.org/10.1007/s10118-020-2492-9
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DOI: https://doi.org/10.1007/s10118-020-2492-9