Abstract
Acrylonitrile/N-[4-(aminosulfonyl)phenyl]acrylamide (AN/ASPAA) copolymers were synthesized and used as a host of lithium ion conducting electrolytes. The composition, molecular weight and molecular weight distribution of AN/ASPAA copolymers were determined, and the influence of copolymer composition on the glass temperature of AN/ASPAA copolymers and the ion conductivity of electrolytes were investigated. The molecular weights of AN/ASPAA copolymers were lower than those of AN and ASPAA homopolymers due to the cross-termination reaction. The glass temperatures of AN/ASPAA copolymers increased as the molar fraction of ASPAA units in copolymers increased. The lithium ion conductivities of the polymer electrolytes increased initially as the molar fraction of ASPAA units in copolymers increased, and a maximum conductivity was achieved when the molar fraction of ASPAA in the copolymer was 16.8%.
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Wang, Y.J., Pan, Y., Wang, L., Pang, M.J. and Chen, L., Mater. Lett., 2005, 59: 3021
Choi, B.K. and Kim, Y.W., Electrochim. Acta, 2004, 49: 2307
Carlsson, P., Swenson, J., Börjesson, L., McGreevy, R.L., Jacobsson, P., Torell, L.M. and Howell, W.S., Electrochim. Acta, 2000, 45: 1449
Carlsson, P., Swenson, J., McGreevy, R.L., Gabrys, B., Howells, W.S., Börjesson, L. and Torell, L.M., Physica B, 1997, 234–236: 231
Wu, G., Yang, H.Y., Chen, H.Z., Yuan, F., Yang, L.G. and Wang, M., Mater. Chem. Phys., 2007, 104: 284
Tian, Z., Pu, W., He, X., Wan, C. and Jiang, C., Electrochim. Acta, 2007, 52: 3199
Vondrk, J., Reiter, J., Velická, J., Klpáště, B., Sedlaříková, M. and Dvořák, J., J. Power Sources, 2005, 146: 436
Uma, T., Mahalingam, T. and Stimming, U., Mater. Chem. Phys., 2005, 90: 245
Sundaram, N.T.K. and Subramania, A., J. Membr. Sci., 2007, 289: 1
Kim, J.R., Choi, S.W., Jo, S.M., Lee, W.S. and Kim, B.C., Electrochim. Acta, 2004, 50: 69
Song, J.Y., Wang, Y.Y. and Wan, C.C., J. Power Sources, 1999, 77: 183
Panero, S. and Scrosati, B., J. Power Sources, 2000, 90: 13
Appetecchi, G.B., Croce, F., Marassi, R., Persi, L., Romagnoli, P. and Scrosati, B., Electrochim. Acta, 1999, 45: 23
Rahman, M.K., Aiba, G., Susan, M.A.B.H. and Watanabe, M., Electrochim. Acta, 2004, 50: 633
Rhaman, M.K., Aiba, G., Susan, M.A. B.H., Sasaya, Y., Octa, K. and Wantanabe, M., Macromolecules, 2004, 37: 5572
Lee, K.H., Lee, Y.G., Park, J.K. and Seung, D.Y., Solid State Ionics, 2000, 133: 257
Zhang, S.S., Ervin, M.H., Xu, K. and Jow, T.R., Solid State Ionics, 2005, 176: 41
Zhang, S.S., Ervin, M.H., Xu, K. and Jow, T.R., Electrochim. Acta, 2004, 49: 3339
Florjańczyk, Z., Zygadlo-Monikowska, E., Wieczorek, W., Ryszawy, A., Tomaszewska, A., Fredman, K., Golodnitsky, D., Peled, E. and Scrosati, B., J. Phys. Chem. B, 2004, 108: 14907
Florjańczyk, Z., Zygadlo-Monikowska, E., Affek, A., Tomaszewska, A., Łasińska, A., Marzantowicz, M., Dygas, J.R. and Krok, F., Solid State Ionics, 2005, 176: 2123
Gao, Y.X., Bao, Y.Z., Huang Z.M. and Weng Z.X., Acta Polymeric Sinica(in Chinese), 2004, (3): 450
Chang, H.L., Chao, T.Y., Yang, C.C., Dai, S.A. and Jeng, R.J., Eur. Polym. J., 2007, 43: 3988
Xiao, S., Huang, Y.M. and Feng, X., Polymer, 2007, 48: 5355
Fox, T.G., Bull. Am. Phys. Soc., 1956, 1: 123
Harwood, H.J., Johnston, N.W. and Piotrowski, H., J. Polym. Sci., Part C: Polym. Symp., 1968, 25(1): 23
Starkey, S.R. and Frech, R., Electrochim. Acta, 1997, 42: 471
Meyer, W.H., Adv. Mater., 1998, 10: 439
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Wang, Ar., Bao, Yz., Weng, Zx. et al. Synthesis and characterization of a novel polymer electrolyte based on acrylonitrile/N-[4-(aminosulfonyl)phenyl]acrylamide copolymers. Chin J Polym Sci 28, 129–135 (2010). https://doi.org/10.1007/s10118-010-9057-2
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DOI: https://doi.org/10.1007/s10118-010-9057-2