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Biodiesel production from scum of grease traps and sludge from septic tanks

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Abstract

Scum from grease traps and sludge from wastewater are an oil-rich waste from the wastewater treatment plants. To mitigate possible negative impacts on the environment, the production of biodiesel from grease traps and sludge from sumps and septic tanks was investigated. These wastes are characterized by a high content of free fatty acids (FFA) and processed towards biodiesel by acidic esterification. The reaction of FFAs by an acid catalyst was optimized through a response surface methodology. The best conversion (95.3%) was obtained with acid catalyser (1.5% w/w oil/4 h) and raw material from the grease trap at the university restaurant at 70 °C and a molar ratio of 1:9 (oil/alcohol). In conclusion, there is viability of biofuels production through the use of sanitation waste as raw material.

Graphical Abstract

Scum and sludge are an oil-rich waste from the sewage treatment plants. To mitigate possible negative impacts on the environment, these raw materials were used as feedstock for biodiesel production.

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References

  • ABNT (2004) Associação Brasileira de Normas Técnicas, Amostragem de Resíduos–procedimento–NBR 10007. São Paulo, Brazil. https://www.abntcatalogo.com.br. Accessed 25 Sept 2015

  • Adewale P, Dumont MJ, Ngadi M (2015) Recent trends of biodiesel production from animal fat wastes and associated production techniques. Renew Sustain Energy Rev 45:574–588

    Article  CAS  Google Scholar 

  • Aitao LI, Thao PN, Jinyong Y, Kaiyuan T, Zhi L (2012) Whole-cell based solvent-free system for one-pot production of biodiesel from waste grease. Bioresour Technol 114:725–729

    Article  Google Scholar 

  • ANP (2010) Brazilian National Agency of Petroleum Natural Gas and Biofuels, Rio de Janeiro, Brazil. www.anp.gov.br/petro/legis_biodiesel.asp. Accessed 08 May 2014

  • AOCS—American Oil Chemists Society (1997) Official method Ca-5a-40- free fatty acids. Boulder, Urbana

    Google Scholar 

  • ASTM—American Society for Testing and Materials (2001) Annual book of ASTM, section 5 petroleum products. Lubricants and Fossil Fuels, West Conshohocken

    Google Scholar 

  • Badday AS, Abdullah AZ, Lee KT (2013) Optimization of biodiesel production process from Jatropha oil using supported heteropolyacid catalyst and assisted by ultrasonic energy. Renew Energy 50:427–432

    Article  CAS  Google Scholar 

  • Balat M (2011) Potential alternatives to edible oils for biodiesel production–a review of current work. Energy Convers Manage 52:1479–1492

    Article  CAS  Google Scholar 

  • Barros AAC, Wust E, Meier HF (2008) Evaluate the waste fatty acid by scientific and technical study to obtain biodiesel. Eng Sanit Ambient 13:255–262

    Article  Google Scholar 

  • Bondioli P (2004) The preparation of fatty acids esters by means of catalytic reactions. Top Catal 27:77–82

    Article  CAS  Google Scholar 

  • Chen X, Du W, Liu D (2008) Response surface optimization of biocatalytic biodiesel production with acid oil. Biochem Eng J 40:423–429

    Article  CAS  Google Scholar 

  • Ezebor F, Khairuddean M, Abdullah AZ, Boey PL (2014) Esterification of oily-FFA and transesterification of high FFA waste oils using novel palm trunk and bagasse-derived catalysts. Energy Convers Manag 88:1143–1150

    Article  CAS  Google Scholar 

  • Freedman B, Pryde EH, Mounts TL (1984) Variables affecting the yields of fatty esters from transesterified vegetable oils. JAOCS 61:1638–1643

    CAS  Google Scholar 

  • Kulkarni MG, Dalai AK (2006) Waste cooking oil—an economical source for biodiesel: a review. Ind Eng Chem Res 45:2901–2913

    Article  CAS  Google Scholar 

  • Kumar G, Kumar D, Johari RP, Singh CP (2011) Enzymatic transesterification of Jatropha curcas oil assisted by ultrasonication. Ultrason Sonochem 18:923–927

    Article  CAS  Google Scholar 

  • Leung DYC, Xuan W, Leung MKH (2010) A review on biodiesel production using catalyzed transesterification. Appl Energy 87:1083–1095

    Article  CAS  Google Scholar 

  • Lucena IL, Saboya RMA, Oliveira JFG, Rodrigues ML, Torres JAEB, Cavalcante CL (2011) Oleic acid esterification with ethanol under continuous water removal conditions. Fuel 90:902–904

    Article  CAS  Google Scholar 

  • Ma LL, Han Y, Sun KA, Lu J, Ding JC (2015) Kinetic and thermodynamic studies of the esterification of acidified oil catalyzed by sulfonated cation exchange resin. J Energy Chem 24:456–462

    Article  Google Scholar 

  • Mello VM, Oliveira FCC, Fraga WG, Nascimento CJ, Suarez PAZ (2008) Determination of the content of fatty acid methyl esters (FAME) in biodiesel samples obtained by esterification using 1H-NMR spectroscopy. Magn Reson Chem 46:1051–1054

    Article  CAS  Google Scholar 

  • Mondala A, Liang K, Toghiani H, Hernandez R, French T (2009) Biodiesel production by in situ transesterification of municipal primary and secondary sludges. Bioresour Technol 100(1203):1210

    Google Scholar 

  • Muhammad NS, Rohani S (2011) Experimental analysis of lipid extraction and biodiesel production from wastewater sludge. Fuel Process Technol 92:2241–2251

    Article  Google Scholar 

  • Oliveira JFG, Lucena IL, Saboya RMA, Rodrigues ML, Torres AEB, Fernandes FAN, Cavalcante CL, Parente EJ (2010) Biodiesel production from waste coconut oil by esterification with ethanol: the effect of water removal by adsorptionRenewable. Energy 35:2581–2584

    CAS  Google Scholar 

  • Oliveira JP, Antunes PWP, Pinotti LM, Cassini STA (2014) Physico-chemical characterization of oily sanitary waste and of oils and greases extracted for conversion into biofuels. Quim Nova 37:597–602

    Google Scholar 

  • Oliveira JP, Antunes PWP, Santos AR, Mordente TZ, Pinotti LM, Cassini STA (2016) Transesterification of Sanitation Waste for Biodiesel production. Waste Biomass Valorization. doi:10.1007/s12649-016-9581-6

    Google Scholar 

  • Ramadhas AS, Jayaraj S, Muraleedharan C (2005) Biodiesel production from high FFA rubber seed oil. Fuel 84:335–340

    Article  CAS  Google Scholar 

  • Revellame E, Hernandez R, French W, Holmes W, Alley E (2010) Biodiesel from activated sludge via in situ transesterification. J Chem Technol Biotechnol 85:614–620

    Article  CAS  Google Scholar 

  • Rhee CH, Martyn PC, Kremer JG (1989) Removal of oil and grease in oil processing wastewater sanitation district of Los Angeles County, U.S.A

  • Sanli H, Canakci M, Alptekin E (2013) Predicting the higher heating values of waste frying oils as potential biodiesel feedstock. Fuel 115:850–854

    Article  Google Scholar 

  • Wiltsee G (1998) Urban waste grease resource assessment. National Renewable Energy Laboratory, Colorado: NREL/SR-570-26141

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Funding

This study was funded by FINEP PROSAB—BRAZIL.

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Correspondence to J. P. Oliveira.

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Oliveira, J.P., Antunes, P.W.P., Mordente, T.Z. et al. Biodiesel production from scum of grease traps and sludge from septic tanks. Clean Techn Environ Policy 19, 1231–1237 (2017). https://doi.org/10.1007/s10098-016-1308-7

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  • DOI: https://doi.org/10.1007/s10098-016-1308-7

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