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Palladium supported on silica gel confined ionic liquid as a reusable catalyst for carbon–carbon cross coupling reaction in water

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Abstract

We have developed an efficient method for carbon–carbon cross coupling reactions using a palladium-catalyst supported on porous silica gel confined ionic liquid, 1-decyl-3-methyl imidazolium fluoroborate ([dmim]BF4) in water at 80 °C. A variety of substituted aryl bromides underwent Suzuki and Heck coupling with various boronic acids and acrylates respectively to produce a series of functionalized biaryls and cinnamates in high yields. The catalyst is stable, recyclable and it offers very high turnover numbers.

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Authors and Affiliations

  1. Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata, 700032, India

    Sudip Ghosh, Raju Dey, Sabir Ahammed & Brindaban C. Ranu

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  1. Sudip Ghosh
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  2. Raju Dey
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  3. Sabir Ahammed
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  4. Brindaban C. Ranu
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Correspondence to Brindaban C. Ranu.

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Ghosh, S., Dey, R., Ahammed, S. et al. Palladium supported on silica gel confined ionic liquid as a reusable catalyst for carbon–carbon cross coupling reaction in water. Clean Techn Environ Policy 16, 1767–1771 (2014). https://doi.org/10.1007/s10098-013-0658-7

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  • DOI: https://doi.org/10.1007/s10098-013-0658-7

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