Abstract
Aqueous oxidation treatment of COD and color in landfill leachate with the combination of hydrogen peroxide and ferrous ion, Fenton reagent, has been studied. The effect of variables such as concentration of both reactants and pH has been investigated. Best concentrations seem to be 0.6 and 3.0 mol/L for H2O2 and Fe2+ ion, respectively. The other important variable, pH of landfill leachate should be near 7. From the experimental results can be known the determined process was the generation of hydroxyl radicals involving in advanced oxidation. Oxidation rates are even higher than those of other advanced oxidation systems involving ozone, UV radiation, and hydrogen peroxide.
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Chitra S, Paramasivan K, Sinha PK (2011) Photodegradation of EDTA using Fenton’s reagent: a pilot-scale study. Res Chem Intermed 37(8):961–974
David LS, Anders WA (1991) Oxidation of chlorobenzene with Fenton’s reagent. Environ Sci Technol 25(4):777
Fernando JB, Gabriel O, Jose ME, Javier R (1995a) Oxidation of polynuclear aromatic hydrocarbons in water. 1. Ozonation. Ind Eng Chem Res 34(5):1596
Fernando JB, Gabriel O, Juan F, Garcia A, Javier R (1995b) Oxidation of polynuclear aromatic hydrocarbons in water. 2. UV radiation and ozonation in the presence of UV radiation. Ind Eng Chem Res 34(5):1607
Fernando JB, Gabriel O, Javier R (1996) Oxidation of polynuclear aromatic hydrocarbons in water. 3. UV radiation combined with hydrogen peroxide. Ind Eng Chem Res 35(3):883
GB 11914-89 (1989) Water quality-determination of the chemical oxygen demand-dichromate method, National Standard of People’s Republic of China
Jasudkar D, Rakhunde R, Deshpande L, Labhasetwar P, Juneja H (2012) Arsenic remediation from drinking water using Fenton’s reagent with slow sand filter. Bull Environ Contam Toxicol 89:1231–1234
Juan ML, Mari FL (2008) Studies on the activation of hydrogen peroxide for color removal in the presence of a new Cu(II)-polyampholyte heterogeneous catalyst. Appl Catal B Environ 82
Kim YO, Nam HU, Park YR, Lee JH, Park TJ, Lee TH (2004) Fenton oxidation process control using oxidation–reduction potential measurement for pigment wastewater treatment. Korean J Chem Eng 21(4):801–805
Lee JC, Kim MS, Kim CK, Chung CH, Cho SM, Han GY, Yoon KJ, Kim BW (2003) Removal of paraquat in aqueous suspension of TiO2 in an immersed UV photoreactor. Korean J Chem Eng 20(5):862
Li HJ, Zhao YC, Shi L (2009) Three-stage aged refuse biofilter for the treatment of landfill leachate. J Environ Sci 21:70–75
Millero FJ, Sotolongo S (1989) The oxidation of Fe(II) with H2O2 in seawater. Geochim Cosmochim Acta 53:1867
Nilesh PT, Sanjeev C (2006) Degradation of azo dyes by sequential Fenton oxidadtion and aerobic biological treatment. J Hazard Mater 13
Ojinnaka C, Osuji L, Achugasim O (2012) Remediation of hydrocarbons in crude oil-contaminated. Environ Monit Assess 184:6527–6540
Pan YX, Zheng HL, Li DD, Gou Q (2008) Degradation of organics in landfill leachate by ultrasound/Fenton process. Chin J Environ Eng 2(4):445–449
Silva PT, Silva VL, de Neto B, Simonnot MO (2009) Phenanthrene and pyrene oxidation in contaminated soils using Fenton’s reagent. J Hazard Mater 161:967–973
Sun HW, Yang Q, Peng YZ (2010) Advanced landfill leachate treatment using a two-stage UASB–SBR system at low temperature. J Environ Sci 22(4):481
Xiao YT, Xu SS, Li ZH (2011) Degradation of polyvinyl-alcohol wastewater by Fenton’s reagent: condition optimization and enhanced biodegradability. J Cent South Univ Technol 18(1):96–100
Yang SJ, He HP (2009) Decolorization of methylene blue by heterogeneous Fenton reaction using Fe3−x Ti x O4 (0 = x = 0.78) at neutral pH values. Appl Catal B Environ 89
Zhang Y, Rong WR, Fu YB, Ma XH (2011) Photocatalytic degradation of poly(vinyl alcohol) on Pt/TiO2 with Fenton’s reagent. J Polym Environ 19(4):966–970
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The authors wish to gratefully acknowledge the financial supports from Jiangxi Provincial Department of Education of China (Project No. GJJ11457). In addition, the authors would like to express their sincere appreciation to the anonymous reviewers for their helpful comments and suggestions.
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Chen, Y., Liu, C., Nie, J. et al. Removal of COD and decolorizing from landfill leachate by Fenton’s reagent advanced oxidation. Clean Techn Environ Policy 16, 189–193 (2014). https://doi.org/10.1007/s10098-013-0627-1
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DOI: https://doi.org/10.1007/s10098-013-0627-1