Abstract
Ammonium removal from the wastewater treatment effluents is mandatory considering the imposed discharge limits and the recycling/reuse requirements. Ion exchange represents a viable alternative for the biological processes of ammonium removal, although concurrent processes make modeling complex. This study reports on the performance of a commercial cation exchange resin, PUROLITE C150H, for ammonium removal from synthetic aqueous solutions. Thermodynamic and kinetic process parameters are calculated using the Langmuir model (thermodynamic study) and the shrinking core model (kinetic study); the data are correlated with the surface properties of the substrate, outlining the adsorption mechanism. For initial ammonium concentrations of 25–150 mg NH4 +/L, removal efficiencies of 80–90 % were obtained.
Similar content being viewed by others
References
Andronic L, Duta A (2008) The influence of TiO2 powder and film on the photodegradation of methyl orange. Mater Chem Phys 112(3):1078–1082
Barjoveanu G, Teodosiu C (2009) Priority organic pollutants removal by ultrafiltration for wastewater recycling. Environ Eng Manag J 8(2):277–287
Bixio D, Thoeye C, De Koning J, Joksimovic D, Savic D, Wintgens T, Melin T (2006) Wastewater reuse in Europe. Desalination 187:89–101
Bradley BR, Daigger GT, Rubin R, Tchobanoglous G (2002) Evaluation of onsite wastewater treatment technologies using sustainable development criteria. Clean Technol Environ Policy 4:87–99. doi:10.1007/s10098-001-0130-y
Cailean D, Teodosiu C (2012) Integrated ultrasonication—ultrafiltration process for the treatment of textile effluents: assessment of operational parameters. Environ Eng Manag J 11(2):259–270
Daverey A, Su S-H, Huang Y-T, Lin J-G (2012) Nitrogen removal from opto-electronic wastewater using the simultaneous partial nitrification, anaerobic ammonium oxidation and denitrification (SNAD) process in sequencing batch reactor. Bioresour Technol 113:225–231
Farkaš A, Rožic M, Barbaric-Mikocevic Ž (2005) Ammonium exchange in leakage waters of waste dumps using natural zeolite from the Krapina region, Croatia. J Hazard Mater B117:25–33
Hamad A, Aidan A, Douboni M (2003) Cost-effective wastewater treatment and recycling in mini-plants using mass integration. Clean Technol Environ Policy 4:246–256. doi:10.1007/s10098-002-0166-7
Hochstrat R, Wintgens T, Melin T (2008) Development of integrated water reuse strategies. Desalination 218:208–217
Inglezakis VJ, Poulopoulos SG (2006) Adsorption, ion exchange and catalysis: design of operations and environmental applications. Elsevier, Amsterdam
Kang SY, Lee J-U, Moon S-H, Kim KW (2004) Competitive adsorption characteristics of Co2+, Ni2+ and Cr3+ by IRN-77 cation exchange resin in synthesized wastewater. Chemosphere 56:141–147
Kauspediene D, Snukiskis J (2006) Sorption kinetics of ammonia and ammonium ions on gel and macroporous sulphonic acid cation exchangers. Sep Purif Technol 50:347–353
Lin LC, Juang RS (2007) Ion-exchange kinetics of Cu(II) and Zn(II) from aqueous solutions with two chelating resins. Chem Eng J 132:205–213
Miladinovic N, Weatherley LR (2008) Intensification of ammonia removal in a combined ion-exchange and nitrification column. Chem Eng J 135:15–24
Öztürk N, Ennil Köse T (2008) A kinetic study of nitrite adsorption onto sepiolite and powdered activated carbon. Desalination 223:174–179
Ramakrishnan A, Surampalli RY (2013) Performance of anaerobic hybrid reactors for the treatment of complex phenolic wastewaters with biogas recirculation. Bioresour Technol 129:26–32
Tchobanoglous G, Burton FL, Stensel HD, Metcalf & Eddy Inc (2003) Wastewater engineering and reuse, 4th edn. McGraw-Hill, New York
Teodosiu C (2002) Water in Europe. Danube River: life line of greater Europe. In: Wilderer P, Huba B, Kotzle T (eds) Advanced treatment and recycling options for industrial effluents, Annals of the European Academy of Sciences and Arts, vol 34. Georg Olms Verlag, Hildesheim, pp 265–289
Thornton A, Pearce P, Parsons SA (2007a) Ammonium removal from digested sludge liquors using ion exchange. Water Res 41:433–439
Thornton A, Pearce P, Parsons SA (2007b) Ammonium removal from solution using ion exchange on to MesoLite, an equilibrium study. J Hazard Mater 147:883–889
Tocchi C, Federici E, Fidati L, Manzi R, Vincigurerra V, Petruccioli M (2012) Aerobic treatment of dairy wastewater in an industrial three-reactor plant: effect of aeration regime on performances and on protozoan and bacterial communities. Water Res 46:3334–3344
Wang Y, Kmiya Y, Okuhara T (2007) Removal of low-concentration ammonia in water by ion-exchange using Na-mordenite. Water Res 41:269–276
Wang Z, Xu X, Gong Z, Yang F (2012) Removal of COD, phenols and ammonium from Lurgi coal gasification wastewater using A 2O-MBR system. J Hazard Mater 235–236:78–84
Zheng H, Han L, Ma H, Zheng Y, Zhang H, Liu D, Liang S (2008) Adsorption characteristics of ammonium ion by zeolite 13X. J Hazard Mater 158:577–584
Acknowledgments
This study was developed with the support of the WATUSER project (“Integrated System for Reducing Environmental and Human Related Impacts and Risks in the Water Use Cycle,” PN-II-PT PCCA-2011-3.2-1491), Contract No. 60/2012 financed by the Romanian Government.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sica, M., Duta, A., Teodosiu, C. et al. Thermodynamic and kinetic study on ammonium removal from a synthetic water solution using ion exchange resin. Clean Techn Environ Policy 16, 351–359 (2014). https://doi.org/10.1007/s10098-013-0625-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10098-013-0625-3