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The evolution of structure–property relationship of P2-type Na0.67Ni0.33Mn0.67O2 by vanadium substitution and organic electrolyte combinations for sodium-ion batteries

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Abstract

Solid-state synthesis of novel electrode materials of P2-type layered oxides Na0.67Ni0.33-xVxMn0.67O2 (where x = 0, 0.05, and 0.11) for the application as cathode materials in rechargeable non-aqueous sodium-ion batteries is reported. Na0.67Ni0.22V0.11Mn0.67O2 electrode delivers significantly improved capacity retention than the pristine P2-Na0.67Ni0.33Mn0.67O2 when cycled between 1.5 and 4.3 V. The effect of organic ester electrolytes with 1.0 M NaClO4 shows diverse effects in the cathode material. The best capacity retention for V-substituted electrodes is observed in ethylene carbonate (EC): propylene carbonate (PC): dimethyl carbonate (DMC) (0.45: 0.45: 0.1) with 1.0 M NaClO4 salt at a C-rate of 0.2C among four different ester electrolytes investigated [PC, EC: PC (1: 1), EC: DEC (1: 1), and EC: PC: DMC (0.45: 0.45: 0.1)].

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Abbreviations

NNMO:

Sodium nickel manganese oxide

NVMO:

Vanadium substituted NNMO

SEI:

Solid electrolyte interphase

EC:

Ethylene carbonate

DEC:

Diethylene carbonate

PC:

Propylene carbonate

FEC:

Fluroethylene carbonate

DMC:

Dimethyl carbonate

XRD:

X-ray diffraction

EPR:

Electron paramagnetic resonance

PVDF:

Poly(vinylidene fluoride)

NMP:

N-Methyl-2-pyrrolidone

SEM:

Scanning electron microscopy

EDX:

Energy-dispersive X-ray

CV:

Cyclic voltammetry

DFT:

Density functional theory

MSD:

Mean square displacement

AIMD:

Ab initio molecular dynamics

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Acknowledgements

This work was supported by funding from the Science & Engineering Research Board (SERB), India, Early Career Research Award (Grant No: ECR/2016/002003). DP acknowledges IIT Kharagpur for the Ph.D. fellowship. DP also thanks Late Prof. Sudipto Ghosh, Department of Metallurgical and Materials Engineering, IIT Kharagpur, for help with electrochemical measurements. DD acknowledges CSIR, New Delhi, for the Ph.D. fellowship.

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  1. School of Energy Science and Engineering, Indian Institute of Technology Kharagpur, Kharagpur, 721302, India

    Debanjana Pahari, Arghadeep Chowdhury, Dhrubajyoti Das & Sreeraj Puravankara

  2. Research Institute for Sustainable Energy, TCG Centres for Research and Education in Science and Technology, Kolkata, 700091, India

    Debanjana Pahari & Tanmoy Paul

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Pahari, D., Chowdhury, A., Das, D. et al. The evolution of structure–property relationship of P2-type Na0.67Ni0.33Mn0.67O2 by vanadium substitution and organic electrolyte combinations for sodium-ion batteries. J Solid State Electrochem 27, 2067–2082 (2023). https://doi.org/10.1007/s10008-023-05466-1

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