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Anodic processes in the alkaline Cu | Cu(II), glycine system—construction and analysis of mass transport–corrected Tafel plots

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Abstract

The anodic behavior of the alkaline Cu | Cu(II), glycine system was investigated by RDE voltammetry combined with EQCM measurements. Well-defined current plateaus were observed on RDE voltammograms in the presence of the excess of ligand. Surface distribution of complexes and ligands in this region was analyzed within the framework of the mass transfer model considering the chemical interactions between species. The degree of surface complexation changes dramatically in the region of pseudo-limiting current due to a sharp decrease in the surface pH and formation of protonated ligands. Entire RDE voltammograms, corrected for mass transport phenomena, were transformed into linear Tafel plots using normalization of the anodic current density relative to the surface concentration of the deprotonated ligand. Empirical Tafel constants were used for estimation of anodic kinetic parameters supposing that the first stage of copper ionization involves the formation of a monoligand copper-glycinate complex.

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Authors and Affiliations

  1. Center for Physical Sciences and Technology, Vilnius, Lithuania

    Arvydas Survila, Stasė Kanapeckaitė & Laurynas Staišiūnas

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  1. Arvydas Survila
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  2. Stasė Kanapeckaitė
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  3. Laurynas Staišiūnas
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Correspondence to Arvydas Survila.

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Survila, A., Kanapeckaitė, S. & Staišiūnas, L. Anodic processes in the alkaline Cu | Cu(II), glycine system—construction and analysis of mass transport–corrected Tafel plots. J Solid State Electrochem 27, 1813–1820 (2023). https://doi.org/10.1007/s10008-022-05365-x

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