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An annular porous column (5) aromatics as anode material for lithium-ion batteries

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Abstract

A column (5) aromatic compound was synthesized and its energy storage behaviors are investigated. The obtained column (5) aromatics is mainly disordered but still contains ordered structures with lattice spacing of 0.287 nm. Such regular layered spacing and molecular-scale voids are very beneficial for the embedding and removal of lithium ions. As a result, the initial charging capacity of column (5) aromatics is only 184 mAh g−1 at current density of 400 mA g−1; as the cycle increased, the charge capacity increased rapidly to 1305 mAh g−1 after 600 cycles. Subsequently, the capacity continued to grow slowly and finally stabilized, when cycling increases to 800 cycles, the capacity is up to 1611 mAh g−1, which is close to its theoretical specific capacity. Meanwhile, a superior rate performance is also observed, at current densities of 0.1, 0.2, 0.5, 1.0, 2.0, and 4.0 A/g, the capacities of column (5) aromatics are 2142, 1951, 1679, 1320, 929, and 484 mAh g−1, respectively. The SEM images show that as the cycle proceeds, the size of the column aromatics particles is significantly reduced and forms a porous and loose morphological structure, which increases the exposed active points, decreases the impedance of the electrode, and gradually increases the cycling capacity.

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Funding

The work was supported by the National Natural Science Foundation of China (21762019), China Postdoctoral Special Grant Program (2021T140138), the Program of Qingjiang Excellent Young Talents in Jiangxi University of Science and Technology (JXUSTQJBJ2019003), Guangdong YangFan Innovative & Entepreneurial Research Team Program (2016YT03N101).

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Author notes

  1. Shihao Fan and Yong Xu contributed equally to this work.

Authors and Affiliations

  1. Jiangxi Provincial Key Laboratory of Power Batteries and Materials, Jiangxi University of Science and Technology, Ganzhou, 341000, People’s Republic of China

    Yong Xu, Zhifeng Li, Chunxiang Wang & Jun Chen

  2. Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou, 341000, People’s Republic of China

    Shihao Fan & Hui Li

Authors
  1. Shihao Fan
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  2. Yong Xu
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  3. Zhifeng Li
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Correspondence to Zhifeng Li.

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Fan, S., Xu, Y., Li, Z. et al. An annular porous column (5) aromatics as anode material for lithium-ion batteries. J Solid State Electrochem 26, 1241–1249 (2022). https://doi.org/10.1007/s10008-022-05162-6

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