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Journal of Solid State Electrochemistry

, Volume 22, Issue 10, pp 3085–3098 | Cite as

Kinetics of island growth in the framework of “planar diffusion zones” and “3D nucleation and growth” models for electrodeposition

  • S. Politi
  • M. Tomellini
Original Paper

Abstract

In the electrochemical deposition of thin films, the measurement of the current-time curve does not allow for a direct determination of the nucleus growth law, electrode surface coverage, and mean film thickness. In this work, we present a theoretical approach suitable to gain insight into these quantities from the knowledge of nucleation density, solution parameters, and current-time behavior. The model applies to both isotropic and anisotropic growth rates of nuclei and a study on the effect of nucleus shape and aspect ratio on the kinetics is presented. Computer simulations and experimental results from literature are also discussed in the framework of the present approach.

Keywords

Kolmogorov-Johnson-Mehl-Avrami theory Phase transformation kinetics Diffusional growth Models of potentiostatic transients 

Notes

Acknowledgements

The authors are indebted with Dr. E. Tamburri for the helpful discussions and the critical reading of the manuscript.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Dipartimento di Scienze e Tecnologie ChimicheUniversità degli studi di Roma Tor VergataRomeItaly
  2. 2.Istituto di Struttura della MateriaCNRRomeItaly

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