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Glassy carbon electrode modified with hemin and new melamine compounds for H2O2 amperometric detection

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Abstract

In an attempt to increase the stability and efficiency of hemin-modified electrodes, the present work reports the preparation of a new modified glassy carbon electrode obtained by immobilization of hemin (Hm) on the electrode surface together with a new N-substituted melamine (2,4,6-triamino-1,3,5-triazine) based G-2 dendrimer comprising p-aminophenol as peripheral unit (Den) or with one of its analogues, a melamine G-0 dimer (Dim). Basic structural features, able to determine intimate relationships between Hm and Dim (or Den) at room temperature in solid state, were evidenced with the use of vibrational analysis carried out by FT-IR. This method revealed contacts between Hm and Dim or Den respectively as H-bond interactions, proton-interchange, and π-π stacking interactions. The new modified electrodes were characterized by cyclic voltammetry and electrochemical impedance spectroscopy and tested for amperometric detection of H2O2. In this purpose, GC/Hm-Dim electrode exhibited better catalytic properties than GC/Hm-Den electrode, but lower stability.

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Notes

  1. According to the definition from Ref.[25], rigid is “fixed in a single conformation either by geometric constraints or because of an overwhelmingly one-sided conformational equilibrium.”

  2. νC=O 1700 cm−1 (in free Hm) but 1713 and 1664 cm−1 in Hm immobilized on Au, Ag(I), and Ag(II) nanoparticles [27, 28].

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Acknowledgments

The financial support from a grant provided by the Research Council Romania (Project PN-II-ID-PCE-2011-3-0128) is gratefully acknowledged. A.B. acknowledges the financial support from the Romanian National Authority for Scientific Research and Innovation (ANCSI) through the Core Program 2015.

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, “Babes-Bolyai” University, Cluj-Napoca, Romania

    Aglaia Raluca Deac, Graziella Liana Turdean & Liana Maria Muresan

  2. Department of Chemistry, “Babes-Bolyai” University, Cluj-Napoca, Romania

    Cristina Morar & Mircea Darabantu

  3. Department of Chemistry and Chemical Engineering, Hungarian Line of Study, “Babes-Bolyai” University, 11 Arany János St., Cluj-Napoca, 400028, Romania

    Emese Gál

  4. Molecular and Biomolecular Physics Department, National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103, Donath St., PO Box 700, Cluj-Napoca 5, 400293, Romania

    Attila Bende

Authors
  1. Aglaia Raluca Deac
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  2. Cristina Morar
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  3. Graziella Liana Turdean
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  4. Mircea Darabantu
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  5. Emese Gál
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  6. Attila Bende
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  7. Liana Maria Muresan
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Correspondence to Liana Maria Muresan.

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Deac, A.R., Morar, C., Turdean, G.L. et al. Glassy carbon electrode modified with hemin and new melamine compounds for H2O2 amperometric detection. J Solid State Electrochem 20, 3071–3081 (2016). https://doi.org/10.1007/s10008-016-3298-0

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  • DOI: https://doi.org/10.1007/s10008-016-3298-0

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