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Selective phosphate sensing using copper monoamino-phthalocyanine functionalized acrylate polymer-based solid-state electrode for FIA of environmental waters

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Abstract

A novel solid-state selective sensor for mono-hydrogen phosphate (HPO4)−2 based on copper monoamino phthalocyanine (CuMAPc) ionophore covalently attached to poly (n-butyl acrylate) (PnBA) has been developed and potentiometrically evaluated. The all solid-state sensor was constructed by the application of a thin film of a polymer cocktail containing a CuMAPc–PBDA ionophore and benzyl-dimethylhexadecyl ammonium chloride (BDMHAC) as a lipophilic cationic additive onto a gold electrode pre-coated with the conducting polymer poly (3,4-ethylenedioxythiophene) (PEDOT) as an ion and electron transducer. The sensor with 14.31 % of CuMAPc-PnBA (ionophore II) exhibited a good selectivity for (HPO4)−2. The thus constructed sensor discriminated many anions, including F−, Cl−, Br−, I–, CH3COO−, NO3 −, ClO4 −, and SO4 2−. The potentiometric response of the phosphate selective electrode was found to be independent of the pH of sample solution in the range 6–9. The sensor showed a Nernstian slope of −29.8 ± 0.3 mV conc.−1 decade−1 with linear range of 4.0 × 10−9–1.0 × 10−2 mol L−1 and detection limit of 1.0 × 10−9 mol L−1 at pH 8.0. The proposed phosphate sensor has been utilized as a detector for the flow injection potentiometric determination of phosphate in different water samples at the nanomolar concentration range.

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Acknowledgments

The authors thank the EU for supporting this work through FP7 Marie Curie IRSES Project: Micro/nanosensors for early cancer warning system—diagnostic and prognostic information “SMARTCANCERSENS” and NATO for supporting this work through project entitled: Novel Electrochemical Nano-Sensors for Toxic Ions Detection Project number: CBP.NUKR.SFP 984173 for supporting this work.

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Authors and Affiliations

  1. Electroanalytical Laboratory, Applied Organic Chemistry Department, National Research Centre, Dokki, Cairo, Egypt

    Mohammad Nooredeen Abbas & Abdel Latief A. Radwan

  2. Polymer and Pigment Department, National Research Centre, Dokki, Cairo, Egypt

    Naglaa M. Nooredeen & Mahmoud A. Abd El-Ghaffar

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  1. Mohammad Nooredeen Abbas
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  2. Abdel Latief A. Radwan
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  3. Naglaa M. Nooredeen
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  4. Mahmoud A. Abd El-Ghaffar
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Correspondence to Mohammad Nooredeen Abbas.

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Abbas, M.N., Radwan, A.L.A., Nooredeen, N.M. et al. Selective phosphate sensing using copper monoamino-phthalocyanine functionalized acrylate polymer-based solid-state electrode for FIA of environmental waters. J Solid State Electrochem 20, 1599–1612 (2016). https://doi.org/10.1007/s10008-016-3165-z

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  • DOI: https://doi.org/10.1007/s10008-016-3165-z

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