Abstract
This work reports on the features that Ni–W nanostructured alloys, electrodeposited on carbon steel by different current pulse programs, may present depending on their surface morphology and surface composition. The Ni–W nanostructured coating, with a cauliflower structure, lack of fragility, and high WO3/W surface composition ratio, is a stable electrode to catalyze hydrogen evolution reaction, exceeding bulk and electrodeposited Ni catalytic activity. Also, the nanostructured alloys must have a low WO3/W surface composition ratio for Ni and its oxides to provide protection and improve corrosion resistance in sulfate media.
Similar content being viewed by others
References
Yamasaki T (2000) Mater Phys Mech 1:127–132
Younes O, Zhu L, Rosenberg Y, Shacham-Diamond Y, Gileadi E (2001) Langmuir 17:8270–8275
Cesiulis H, Baltutiene A, Donten M, Donten ML, Stojek Z (2002) J Solid State Electrochem 6:237–244
Yang F-Z, Guo Y-F, Huang L, Xu S-K, Zhou S-M (2004) Chin J Chem 22:228–231
Sriraman KR, Ganesh Sundara Raman S, Seshadri SK (2006) Mater Sci Eng A 418:303–311
Sriraman KR, Ganesh Sundara Raman S, Seshadri SK (2007) Mater Sci Eng A 460–461:39–45
Detor AJ, Schuh CA (2007) Acta Mater 55:371–379
Alimadadi H, Ahmadi M, Aliofkhazraei M, Younesi SR (2009) Mater Des 30:1356–1361
Cardinal MF, Castro PA, Baxi J, Liang H, Williams FJ (2009) Surf Coat Technol 204:85–90
de Lima-Neto P, Correia AN, Santana RAC, Colares RP, Barros EB, Casciano PNS, Vaz GL (2010) Electrochim Acta 55:2078–2086
Quiroga Argañaraz MP, Ribotta SB, Folquer ME, Gassa LM, Benítez G, Vela ME, Salvarezza RC (2011) Electrochim Acta 56:5898–5903
Zemanová M, Krivosudská M, Chovancová M (2011) J Appl Electrochem 41:1077–1085
Chianpairot A, Lothongkum G, Schuh CA, Boonyongmaneerat Y (2011) Corros Sci 53:1066–1071
Farzaneh MA, Zamanzad-Ghavidel MR, Raeissi K, Golozar MA, Saatchi A, Kabi S (2011) Appl Surf Sci 257:5919–5926
Obradović MD, Stevanović J, Stevanović RM, Despić AR (2000) J Electroanal Chem 491:188–196
Younes O, Gileadi E (2002) J Electrochem Soc 149(2):C100–C111
Younes-Metzler O, Zhu L, Gileadi E (2003) Electrochim Acta 48:2551–2562
Obradović MD, Bošnjakov GŽ, Stevanović RM, Maksimović MD, Despić AR (2006) Surf Coat Technol 200:4201–4207
Zhu L, Younes O, Ashkenasy N, Shacham-Diamond Y, Gileadi E (2002) Appl Surf Sci 200:1–14
Yamasaki T, Schloβmacher P, Ehrlich K, Ogino Y (1998) Nanostruct Mater 10:375–388
Krolikowski A, Plonska E, Ostrowski A, Donten M, Stojek Z (2009) J Solid State Electrochem 13:263–275
Donten M, Cesiulis H, Stojek Z (2000) Electrochim Acta 45:3389–3396
Younes O, Gileadi E (2000) Electrochem Solid State Lett 3:543–545
Obradović M, Stevanović J, Despić A, Stevanović R, Stoch J (2001) J Serb Chem Soc 66(11–12):899–912
Sassi W, Dhouibi L, Berçot P, Rezrazi M, Triki E (2012) Surf Coat Technol 206:4235–4241
Quiroga Argañaraz MP, Ribotta SB, Folquer ME, Zelaya E, Llorente C, Ramallo-López JM, Benítez G, Rubert A, Gassa LM, Vela ME, Salvarezza RC (2012) Electrochim Acta 72:87–93
Lucente AM, Scully JR (2007) Corros Sci 49:2351–2361
Acosta CC, Salvarezza RC, Videla HA, Arvia AJ (1985) Corros Sci 25:291–303
Jones DA (1992) Principles and prevention of corrosion. Macmillan, New York
Juškėnas R, Valsiũnas I, Pakštas V, Giraitis R (2009) Electrochim Acta 54:2616–2620
Harnisch F, Sievers G, Schröder U (2009) Appl Catal B Environ 89:455–458
Lin S-C, Chiu Y-F, Wu P-W, Hsieh Y-F, Wu C-Y (2010) J Mater Res 25:2001–2007
Savadogo O, Ndzebet E (1993) J Appl Electrochem 23:915–921
Savadogo O (1993) Mater Chem Phys 35:145–150
Abbaro SA, Tseung ACC, Hibbert DB (1980) J Electrochem Soc 127:1106–1107
Metikoš-Huković M, Grubač Z, Radić N, Tonejc A (2006) J Mol Catal Chem 249:172–180
Zheng H, Mathe M (2011) Int J Hydrogen Energy 36:1960–1964
Gassa LM, Vilche JR, Arvia AJ (1983) J Appl Electrochem 13:135–145
Barral G, Njanjo-Eyoke F, Maximovitch S (1995) Electrochim Acta 40:709–718
Ortiz PI, López Teijelo M, Giordano MC (1988) J Electroanal Chem 243:379–391
Anik M, Osseo-Asare K (2002) J Electrochem Soc 149:B224–B233
Anik M (2010) Corros Sci 52:3109–3117
Acknowledgments
We acknowledge financial support from the Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET, PIP 03079), the Agencia Nacional para la Promoción de la Ciencia y la Tecnología Argentina (ANPCyT, PICT 2010-2554, PICT CNPQ-0019), and Consejo de Investigaciones de la Universidad Nacional de Tucumán, Argentina. MEV is member of the research career of CICPBA, Argentina.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Quiroga Argañaraz, M.P., Ribotta, S.B., Folquer, M.E. et al. The electrochemistry of nanostructured Ni–W alloys. J Solid State Electrochem 17, 307–313 (2013). https://doi.org/10.1007/s10008-012-1965-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-012-1965-3