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Applications of coulometric titration for studies of oxygen non-stoichiometry in oxides

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Abstract

This article gives a brief overview of the modern methods for in situ studying of oxygen non-stoichiometry in oxides. The emphasis is on the techniques that are based on the use of transport properties of solid electrolytes with unipolar oxygen ion conductivity, as well as on the experimental implementation of coulometric titration. The possible sources of experimental errors are considered, and methods are discussed of their accounting and minimization. Several examples are given of the using of the data on non-stoichiometry for the determination of thermodynamic properties and defect structure in oxides.

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Acknowledgements

The authors greatly appreciate the partial support of this work by the Ural Branch of Russian Academy of Science.

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  1. Institute of Solid State Chemistry, Ural Branch of RAS, 91 Pervomaiskaya Str., Yekaterinburg, Russia

    Mikhail V. Patrakeev, Ilia A. Leonidov & Victor L. Kozhevnikov

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  1. Mikhail V. Patrakeev
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  2. Ilia A. Leonidov
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Correspondence to Mikhail V. Patrakeev.

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Patrakeev, M.V., Leonidov, I.A. & Kozhevnikov, V.L. Applications of coulometric titration for studies of oxygen non-stoichiometry in oxides. J Solid State Electrochem 15, 931–954 (2011). https://doi.org/10.1007/s10008-010-1111-z

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