Abstract
Conducting and stable poly (N-methylaniline) film was prepared by using the repeated potential cycling technique in aqueous solution containing N-methylaniline, sulfuric acid, and sodium dodecyl sulfate (SDS) at the surface of carbon paste electrode (CPE). The transition metal ions of Co(ІІ) were incorporated to the polymer by immersion of the modified electrode in 0.1 M cobalt chloride solution for 10 min. The electrochemical characterization of this modified electrode exhibits stable redox behavior of Co(ІІ)→Co(ІІІ) and formation of insoluble oxide/hydroxide cobalt species on the CPE surface. The modified electrode showed well-defined and stable redox couples in alkaline aqueous solution. The modified electrode showed excellent electrocatalytic activity for oxidation of hydrogen peroxide. The response of modified electrode toward the H2O2 oxidation was examined using cyclic voltammetry, differential pulse voltammetry, square wave voltammetry, and chronoamperometry. This modified electrode has many advantages such as simple preparation procedure, good reproducibility, and high catalytic activity toward the hydrogen peroxide oxidation. Such characteristics were explored for the specific determination of hydrogen peroxide in cosmetics product sample, giving results in excellent agreement with those obtained by standard method.
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Yamamoto H, Oshima M, Hosaka T, Isa I (1999) Synth Met 104:33. doi:10.1016/S0379-6779(99) 00003-X
Malinauskas A, Holze R, Bunsenges B (1997) Phys Chem 101:1859
Malinauskas A, Holze R (1999) Electrochim Acta 44:2613. doi:10.1016/S0013-4686(98) 00390-9
Barbero C, Miras MC, Hass O, Kotz R (1991) J Electroanal Chem 310:437. doi:10.1016/0022-0728(91) 85280-3
Naoi K, Oura Y, Maeda M, Nakamura S (1995) J Electrochem Soc 142:417. doi:10.1149/1.2044042
Moussa I, Hedayatullah M, Aaron JJ (1998) J Chim Phys 95:1551. doi:10.1051/jcp:1998326
Okahata Y, Enna G, Taguchi K, Seki T (1985) J Am Chem Soc 107:5300. doi:10.1021/ja00304a060
Sun H, Ma H, Hu N (1999) Bioelectrochem Bioenerg 49:1. doi:10.1016/S0302-4598(99) 00060-4
Liu H, Wang L, Hu N (2002) Electrochim Acta 47:2515. doi:10.1016/S0013-4686(02) 00128-7
Ogawa K, Wang B, Kokufuta E (2001) Langmuir 17:4704. doi:10.1021/la0102354
Wang J (2001) Electroanalyasis 13:983. doi:10.1002/1521-4109(200108) 13:12<983::AID-ELAN983>3.0.CO;2-#
Vogel AI (1989) Textbook of quantitative chemical analysis. Longman, UK
Armstrong FA, Lanon AM (1985) J Am Chem Soc 109:7211. doi:10.1021/ja00257a063
Darder M, Takada K, Pariente F, Lorenzo E, Abruna HD (1999) Anal Chem 71:5530. doi:10.1021/ac990759x
Xu G, Dong S (1999) Electroanalysis 11:1180. doi:10.1002/(SICI) 1521-4109(199911) 11:16<1180::AID-ELAN1180>3.0.CO;2-T
Mashazi PN, Ozoemena KI, Nyokong T (2006) Electrochim Acta 52:177. doi:10.1016/j.electacta.2006.04.056
Wang B, Dong S (2000) Talanta 51:565. doi:10.1016/S0039-9140(99) 00315-X
Cox JA, Jaworski RK (1989) Anal Chem 61:2176. doi:10.1021/ac00194a012
Domenech A, Alarcon J (2002) Anal Chim Acta 452:11. doi:10.1016/S0003-2670(01) 01430-1
Rezwan MM, Ohsaka T (2006) Anal Chem 78:1200. doi:10.1021/ac0515935
Fiorito PA, De Torresi SIC (2004) Talanta 62:649. doi:10.1016/j.talanta.2003.09.010
Morrin A, Moutloali RM, Killard AJ, Smyth MR, Darkwa J, Iwuoha EI (2004) Talanta 64:30. doi:10.1016/j.talanta.2003.11.046
Sotomayor MPDT, Tanaka AA, Kubota IT (2003) Electrochim Acta 48:855. doi:10.1016/S0013-4686(02) 00777-6
Song Y, Wang L, Ren C, Zhu G, Li Z (2006) Sens Actuators B Chem 114:1001. doi:10.1016/j.snb.2005.07.061
Yang R, Ruan C, Dai W, Deng J, Kong J (1998) Electrochim Acta 44:1585. doi:10.1016/S0013-4686(98) 00283-7
Wang B, Zhang J, Cheng G, Dong S (2000) Anal Chim Acta 407:111. doi:10.1016/S0003-2670(99) 00778-3
Xu JJ, Zhou DM, Chen HY (1998) Electroanalysis 10:713. doi:10.1002/(SICI) 1521-4109(199808) 10:10<713::AID-ELAN713>3.0.CO;2-6
Ueda Y, Kikuchi N, Ikeda S, Houga T (1999) J Magn Mater 198:740. doi:10.1016/S0304-8853(98) 01024-5
Yoshino T, Baba N (1995) Sol Energy Mater Sol Cells 39:391. doi:10.1016/0927-0248(96) 80004-3
Monk PMS, Ayub S (1997) Solid State Ion 99:115. doi:10.1016/S0167-2738(97) 00148-3
Hutchins MG, Wright PJ, Grebenik PD (1987) Sol Energy Mater 16:113. doi:10.1016/0165-1633(87) 90013-X
Barrera E, Gonzales I, Viveros T (1988) Sol Energy Mater Sol Cells 51:69. doi:10.1016/S0927-0248(97) 00209-2
Behl WK, Toni JE (1971) J Electroanal Chem 31:63. doi:10.1016/S0022-0728(71) 80043-8
Burke LD, Lyons ME, Murphy OJ (1982) J Electroanal Chem 132:247. doi:10.1016/0022-0728(82) 85022-5
Cataldi TRI, Guerrieri A, Casella IG, Desimoni E (1995) Electroanalysis 7:305. doi:10.1002/elan.1140070402
Casella IG, Guascito MR (1999) Electrochim Acta 45:1113. doi:10.1016/S0013-4686(99) 00315-1
Spinolo G, Ardizzone S, Trasatti S (1997) J Electroanal Chem 423:49. doi:10.1016/S0022-0728(96) 04841-3
Elbaydi M, Poillerat G, Rehspringer JL, Gautier JL, Koening JF, Chartier P (1994) J Solid State Chem 109:281. doi:10.1006/jssc.1994.1105
Svegl F, Orel B, Hutchins MG, Kalcher K (1996) J Electrochem Soc 143:1532. doi:10.1149/1.1836675
Serebrennikova I, Birss VI (1997) J Electrochem Soc 144:566. doi:10.1149/1.1837449
Singh RN, Koening JF, Poillerat G, Chartier P (1990) J Electrochem Soc 137:1408. doi:10.1149/1.2086682
Nkeng P, Koening JF, Gautier JL, Chartier P, Poillerat G (1996) J Electroanal Chem 402:81. doi:10.1016/0022-0728(95) 04254-7
Nkeng P, Poillerat G, Koening JF, Chartier P, Lefez B, Lopitaux J, Lenglet M (1995) J Electrochem Soc 142:1777. doi:10.1149/1.2044193
Schumacher LC, Hill IR, Dignam MJ (2002) Electrochim Acta 35:975. doi:10.1016/0013-4686(90) 90030-4
Ojani R, Raoof JB, Salmany-Afagh P (2004) J Electroanal Chem 571:1. doi:10.1016/j.jelechem.2004.03.032
Ojani R, Raoof JB, Hosseini Zavvarmahalleh SR (2008) Electrochim Acta 53:2402. doi:10.1016/j.electacta.2007.10.004
Vittal R, Gomathi H, Rao GP (2001) J Electroanal Chem 497:47. doi:10.1016/S0022-0728(00) 00381-8
Bard AJ, Faulkner LR (2001) Electrochemical methods. Wiley, New York
Laviron E (1979) J Electroanal Chem 101:19. doi:10.1016/S0022-0728(79) 80075-3
Cui X, Hong L, Lin X (2002) J Electroanal Chem 526:115. doi:10.1016/S0022-0728(02) 00724-6
Casella IG (2002) J Electroanal Chem 520:119. doi:10.1016/S0022-0728(02) 00642-3
Salimi H, Hallaj R, Soltanian S, Mamkhezri H (2007) Anal Chim Acta 594:24. doi:10.1016/j.aca.2007.05.010
Lin Y, Cui X, Li L (2005) Electrochem Commun 7:166. doi:10.1016/j.elecom.2004.12.005
Guascito MR, Filippo E, Malitesta C, Manno D, Serra A, Turco A (2008) Biosens Bioelectron 24:1057. doi:10.1016/j.bios.2008.07.048
Zhu S, Fan L, Liu X, Shi L, Li H, Han S, Xu G (2008) Electrochem Commun 10:695. doi:10.1016/j.elecom.2008.02.020
Brezina M, Koryta J, Loueka T, Marsikova D, Pradac J (1972) J Electroanal Chem 40:13. doi:10.1016/S0022-0728(72) 80121-9
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Ojani, R., Raoof, JB. & Norouzi, B. Carbon paste electrode modified by cobalt ions dispersed into poly (N-methylaniline) preparing in the presence of SDS: application in electrocatalytic oxidation of hydrogen peroxide. J Solid State Electrochem 14, 621–631 (2010). https://doi.org/10.1007/s10008-009-0824-3
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DOI: https://doi.org/10.1007/s10008-009-0824-3