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Preparation and characterization of a new carbon paste electrode based on ketotifen–hexacyanoferrate

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Abstract

A new type of carbon paste electrode (CPE) was made using ketotifen fumarate (C23H23NO5S; an antiasthmatic/antianaphylactic drug) and hexacyanoferrate. This electrode was constructed using an acidic solution of ketotifen fumarate and potassium hexacyanoferrate. For this purpose, ketotifen fumarate was dissolved in acidic solution (pH 1) and hexacyanoferrate was added by agitation, resulting in ketotifen–hexacyanoferrate (Ket–HCF) precipitate. The obtained precipitate was separated and introduced into carbon paste. The electrochemical behavior of Ket–HCF CPE was studied by cyclic voltammetry. A modified electrode shows one pair of peaks with surface-confined characteristics, with a 0.1-M phosphate buffer as supporting electrolyte. The effects of pH, alkali metal cations, and anions of supporting electrolytes on the electrochemical characteristics of modified electrodes were studied. The diffusion coefficients of hydrated K+ in film (D), the transfer coefficient (α), and the transfer rate constant for electrons (k s) were determined.

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References

  1. Tao W, Pan D, Liu Y, Nie L, Yao S (2004) J Electroanal Chem 572:109

    Article  CAS  Google Scholar 

  2. Pournaghi-Azar MH, Sabzi RE (2004) Electroanalysis 16:860

    Article  CAS  Google Scholar 

  3. Umezawa Y, Umezawa K, Buhlmann P, Hamada N, Aoki H, Nakanishi J, Sato M, Xiao KP, Nishimura Y (2002) Pure Appl Chem 74:923

    CAS  Google Scholar 

  4. Umezawa Y, Buhlmann P, Umezawa K, Hamada N (2002) Pure Appl Chem 74:995

    CAS  Google Scholar 

  5. Takada K, Inada T, Kajiyama A, Kouguchi M, Sasaki H, Kondo S, Michiue Y, Nakano S, Tabuchi M, Watanabe M (2005) Solid State Ionics 172:25

    Article  CAS  Google Scholar 

  6. Yang Y, Yang H, Yang M, Liu Y, Shen G, Yu R, (2004) Anal Chim Acta 525:213

    Article  CAS  Google Scholar 

  7. Chaniotakis NA (2004) Anal Bioanal Chem 378:89

    Article  PubMed  CAS  Google Scholar 

  8. Pei J, Li XY (1999) Electroanalysis 11:1266

    Article  CAS  Google Scholar 

  9. Pournaghi-Azar MH, Sabzi RE (2002) J Solid State Electrochem 6:553

    Article  CAS  Google Scholar 

  10. Cataldi TRI, Benedetto GED, Bianchini A (1998) Electroanalysis 10:1163

    Article  CAS  Google Scholar 

  11. Chen SM, Chan CM (2003) J Electroanal Chem 543:161

    Article  CAS  Google Scholar 

  12. Klein LJ, Alleman KS, Peters DG, Karty JA, Reilly JP (2000) J Electroanal Chem 481:24

    Article  CAS  Google Scholar 

  13. Filanovsky B (1999) Anal Chim Acta 394:91

    Article  CAS  Google Scholar 

  14. Choi YK, Park JK, Jeon S (1999) Electroanalysis 11:134

    Article  CAS  Google Scholar 

  15. Sabzi RE, Pournaghi-Azar MH (2005) Anal Sci 21:689

    Article  PubMed  CAS  Google Scholar 

  16. Cui X, Hong L, Lin X (2002) J Electroanal Chem 526:115

    Article  CAS  Google Scholar 

  17. Neff VD (1978) J Electrochem Soc 125:886

    Article  CAS  Google Scholar 

  18. Itaya K, Uchida I, Neff VD (1986) Acc Chem Res 19:162

    Article  CAS  Google Scholar 

  19. Luangdilok CH, Arnet DJ, Bocarsly AB, Wood R (1992) Langmuir 8:650

    Article  CAS  Google Scholar 

  20. Lin MS, Shih WC (1999) Anal Chim Acta 381:183

    Article  CAS  Google Scholar 

  21. Xu F, Gao M , Wang L, Zhou T, Jin L, Jin J (2002) Talanta 58:427

    Article  CAS  Google Scholar 

  22. Kulseza PJ, Malik MA, Berrettoni M, Giorgetti M, Zamponi S, Schmidt R, Marassi R (1998) J Phys Chem B 102:1870

    Article  Google Scholar 

  23. Kulseza PJ, Zamponi S, Malik MA, Berrettoni M, Wolkiewicz A, Marassi R (1998) Electrochim Acta 43:919

    Article  Google Scholar 

  24. Cai CX, Ju HX, Chen HY (1995) J Electroanal Chem 397:185

    Article  Google Scholar 

  25. Wang J, Zhang X, Chen L (2000) Electroanalysis 12:1277

    Article  CAS  Google Scholar 

  26. Wang J, Zhang X, Prakash M (1999) Anal Chim Acta 395:11

    Article  CAS  Google Scholar 

  27. Kahlert H, Retter U, Lohse H, Siegler K, Scholz F (1998) J Phys Chem B 102:8757

    Article  CAS  Google Scholar 

  28. Siperko LM, Kuwana T (1987) Electrochim Acta 32:765

    Article  CAS  Google Scholar 

  29. Eftekhari A (2004) J Electrochem Soc 151:E297

    Article  CAS  Google Scholar 

  30. Tacconi NRD, Rajeshwar K, Lezna RO (2001) J Electroanal Chem 500:270

    Article  Google Scholar 

  31. Cataldi TRI, Benedetto GED, Bianchini A (1998) J Electroanal Chem 448:111

    Article  CAS  Google Scholar 

  32. Liu SQ, Chen HY (2002) J Electroanal Chem 528:190

    Article  CAS  Google Scholar 

  33. Wang P, Jiang X, Zhang W, Zhu G (2001) J Solid State Electrochem 5:369

    Article  CAS  Google Scholar 

  34. Dong S, Jiu Z (1988) J Electroanal Chem 256:193

    Article  CAS  Google Scholar 

  35. Vittal R, Gomathi H, Rao GP (2000) Electrochim Acta 45:2083

    Article  CAS  Google Scholar 

  36. Narayanan SS, Scholz F (1999) Electroanalysis 11:465

    Article  CAS  Google Scholar 

  37. Pournaghi-Azar MH, Razmi-Nerbin H (1998) J Electroanal Chem 456:83

    Article  CAS  Google Scholar 

  38. Pournaghi-Azar MH, Dastangoo H (2002) J Electroanal Chem 523:26

    Article  CAS  Google Scholar 

  39. Liu S, Li H, Jiang M, Li P (1997) J Electroanal Chem 426:27

    Article  CAS  Google Scholar 

  40. Wu P, Cai C (2004) J Solid State Electrochem 8:538

    Article  CAS  Google Scholar 

  41. Eftekhari A (2001) Anal Lett 34:541

    Article  CAS  Google Scholar 

  42. Mishma Y, Motonaka J, Maruyama K, Ikeda S (1998) Anal Chim Acta 358:291

    Article  Google Scholar 

  43. Liu C, Dong S (1997) Electroanalysis 9:838

    Article  CAS  Google Scholar 

  44. Eftekhari A (2002) J Electroanal Chem 537:59

    Article  CAS  Google Scholar 

  45. Joseph J, Gomathi H, Rao GP (1997) J Electroanal Chem 431:231

    Article  CAS  Google Scholar 

  46. Liu SQ, Chen Y, Chen HY (2001) J Electroanal Chem 502:197

    Article  CAS  Google Scholar 

  47. http://www.pharmtech.com.cn/sinoparm/ketotifenfumarate.html

  48. Greiner JV, Mundorf T, Dubiner H, Lonsdale J, Casey R, Parver L, Kapik BM, Shams NBK, Ableson MB (2003) Am J Ophthalmol 136:1097

    Article  PubMed  CAS  Google Scholar 

  49. Abounassif MA, El-Obeid HA, Gadkariem EA (2005) J Pharm Biomed Anal 36:1011

    Article  PubMed  CAS  Google Scholar 

  50. Elena PP, Amex T, Schoch C (1998) Invest Ophthalmol Vis Sci 39:S549

    Google Scholar 

  51. Miki I, Kusano A, Ohta S (1996) Cell Immunol 171:285

    PubMed  CAS  Google Scholar 

  52. Lee Y, Chiang C, Chen J (1994) Drug Dev Ind Pharm 20:2965

    CAS  Google Scholar 

  53. Laviron E (1979) J Electroanal Chem 101:19

    Article  CAS  Google Scholar 

  54. Dong S, Jin Z (1989) Electrochim Acta 34:963

    Article  CAS  Google Scholar 

  55. Bard AJ, Faulkner LR (2001) Electrochemical methods: fundamentals and applications. Wiley, New York, p 236

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Urmia University, Urmia, Iran

    G. Tabrizivand, R. E. Sabzi & K. Farhadi

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  1. G. Tabrizivand
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  2. R. E. Sabzi
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  3. K. Farhadi
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Correspondence to R. E. Sabzi.

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Tabrizivand, G., Sabzi, R.E. & Farhadi, K. Preparation and characterization of a new carbon paste electrode based on ketotifen–hexacyanoferrate. J Solid State Electrochem 11, 103–108 (2007). https://doi.org/10.1007/s10008-005-0077-8

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  • DOI: https://doi.org/10.1007/s10008-005-0077-8

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