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The solid state electrochemistry of samarium (III) hexacyanoferrate (II)

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Abstract

A new electroactive polynuclear inorganic compound of a rare earth metal hexacyanoferrate, samarium hexacyanoferrate (SmHCF), was prepared chemically and characterized using techniques of FTIR spectroscopy, thermogravimetric analysis (TGA), X-ray powder diffraction, UV–Vis spectrometry and X-ray photoelectron spectroscopy (XPS) etc. The cyclic voltammetric behavior of SmHCF mechanically attached to the surface of graphite electrode was well defined and exhibited a pair of redox peaks with the formal potential of 180.5 mV (versus SCE) at a scan rate of 100 mV/s in 0.2-M NaCl solution and the redox peak currents increased linearly with the square root of the scan rates up to as high as 1,000 mV/s. The effects of the concentration of supporting electrolyte on the electrochemical characteristics of SmHCF and the transport behavior of K+, Na+ and Li+ counter-ions through the ion channel of SmHCF were studied by voltammetry.

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Acknowledgements

The authors are grateful for the financial support of the National Natural Science Foundation of China (20373027), the foundation for scientists returned from abroad directed under the State Ministry of Education of China, the Natural Science Foundation of Education Committee of Jiangsu Province (03KJA150055) and the Excellent Talent Project of Personnel Department of Nanjing City of Jiangsu Province.

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  1. Department of Chemistry, Nanjing Normal University, 210097, Nanjing, P.R. China

    Ping Wu & Chenxin Cai

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  1. Ping Wu
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  2. Chenxin Cai
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Correspondence to Chenxin Cai.

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Wu, P., Cai, C. The solid state electrochemistry of samarium (III) hexacyanoferrate (II). J Solid State Electrochem 8, 538–543 (2004). https://doi.org/10.1007/s10008-003-0481-x

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  • DOI: https://doi.org/10.1007/s10008-003-0481-x

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