Evaluation of combined measurement uncertainty of the determination of Mn content in sediment samples

Abstract 

Combined uncertainties of an analysis of elemental content of sediment samples were evaluated. A monitoring system has been designed and implemented for the characterization of the environmental conditions of Lake Balaton in Hungary. Sediments samples were collected and an acidic digestion method was used to determine the concentration of elements. For the calculation of the result of each measurement three different approaches were considered, namely a.) the calculation of the result using a calibration curve and estimating the confidence limit by the Student t-distribution, b.) calculation of the combined uncertainty and c.) estimation of the sampling errors using the transport and field blanks. The latter approach gave the most reliable result since it included all the parameters which had to be considered regarding sampling and sample handling, and measurement. Determination of acid soluble Mn content in sediment samples has been chosen as an example, and the combined uncertainty is calculated using blanks for sampling.