Skip to main content
Log in

Trends in the development of proficiency testing for chemical analysis: focus on food and environmental matrices

  • General Paper
  • Published:
Accreditation and Quality Assurance Aims and scope Submit manuscript

Abstract

The importance of quality in analytical chemistry stimulates the development of different tools to assure the reliability of analytical results. Among different tools, proficiency testing (PT) stands out because it can be used to evaluate bias, check uncertainty, train analysts, or certify if a laboratory can execute a method adequately and provide correct results. There is a growing demand for traceable and reliable results in analytical chemistry, which can be illustrated with the growth of ISO/IEC 17025 accreditation and the importance of PT in this context. This has led to an increase in developments and publications about PT programs. This paper reports a detailed review considering the best practices to develop PT for chemical analysis, focusing on food and environmental matrices. An evaluation of the trends and the statistical strategies in its development in the last two years was performed to guide new developments of this tool that is increasingly necessary for laboratories.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

Availability of data and material

Not applicable.

Code availability

Not applicable.

References

  1. Valcarável M, Rios A (1994) Analytical chemistry and quality. Trac Trends Anal Chem. https://doi.org/10.1016/0165-9936(94)85055-0

    Article  Google Scholar 

  2. Olivares IRB, Lopes FA (2012) Essential steps to providing reliable results using the analytical quality assurance cycle. Trac Trends Anal Chem. https://doi.org/10.1016/j.trac.2012.01.004

    Article  Google Scholar 

  3. Taverniers I, De Loose M, Van Bockstaele E (2004) Trends in quality in the analytical laboratory. II. Analytical method validation and quality assurance. Trac Trends Anal Chem. https://doi.org/10.1016/j.trac.2004.04.001

    Article  Google Scholar 

  4. ISO/IEC 17025:2017 General requirements for the competence of testing and calibration laboratories. Geneva

  5. OECD (1998) Series on principles of good laboratory practice and compliance monitoring—number 1: principles on good laboratory practice. Paris

  6. ISO 15189:2015 Medical laboratories—requirements for quality and competence. Geneva

  7. ILAC (2020) Facts and figures. https://ilac.org/about-ilac/facts-and-figures/. Accessed Mach 2020

  8. Olivares IRB (2016) Laboratory quality management. Editora Átomo, Campinas

    Google Scholar 

  9. ILAC (2014) Policy for participation in proficiency testing activities. https://ilac.org/latest_ilac_news/ilac-p9062014-published/. Accessed Mach 2020

  10. ISO 13528:2015 Statistical methods for use in proficiency testing by interlaboratory comparison. Geneva

  11. ISO/IEC 17043:2010 Conformity assessment-general requirements for proficiency testing. Geneva

  12. Zailer E, Monakhova YB, Diehl BWK (2018) 31P NMR method for phospholipid analysis in krill oil: proficiency testing-a step toward becoming an official method. J Am Oil Chem Soc. https://doi.org/10.1002/aocs.12153

    Article  Google Scholar 

  13. Yeltepe E, Şahin NK, Aslan N, Hult M, Özçayan G, Wershofen H, Yücel Ü (2018) A review of the TAEA proficiency test on natural and anthropogenic radionuclides activities in black tea. Appl Radiat Isotopes. https://doi.org/10.1016/j.apradiso.2017.10.011

    Article  Google Scholar 

  14. Yarita T, Otake T, Aoyagi Y, Takasaka N, Suzuki T, Watanabe T (2018) Comparison of assigned values from participants’ results, spiked concentrations of test samples, and isotope dilution mass spectrometric results in proficiency testing for pesticide residue analysis. J AOAC Int. https://doi.org/10.5740/jaoacint.17-0218

    Article  PubMed  Google Scholar 

  15. Esen AN, Haciyakupoglu S, Erenturk S (2017) Comparison of relative INAA and k0-INAA using proficiency test materials at ITU TRIGA Mark II research reactor. J Radioanal Nucl Chem. https://doi.org/10.1007/s10967-017-5669-0

    Article  Google Scholar 

  16. Wiedner H, Riedl J, Maringer FJ, Baumgartner A, Stietka M, Kabrt F (2018) Production and characterization of a traceable NORM material and its use in proficiency testing of gamma-ray spectrometry laboratories. Appl Radiat Isotopes. https://doi.org/10.1016/j.apradiso.2017.09.025

    Article  Google Scholar 

  17. Nakashima N, Duran EB (2018) Proficiency test exercises for particulate systems at CTBT radionuclide laboratories. Appl Radiat Isotopes. https://doi.org/10.1016/j.apradiso.2017.07.034

    Article  Google Scholar 

  18. Stöckel S, Cordes J, Stoffles B, Wildanger D (2018) Scents in the stack: olfactometric proficiency testing with an emission simulation apparatus. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-018-2515-z

    Article  Google Scholar 

  19. Cordeiro F, Bratinova S, Karasek L, Buttinger G, Stroka J, Emteborg H, Seghers J, Robouch P, Emons H (2019) Can official control laboratories quantify reliably fipronil in eggs? Evidence from a proficiency testing round. Food Addit Contam. https://doi.org/10.1080/19440049.2019.1602885

    Article  Google Scholar 

  20. Thompson M, Sykes M, Wood R (2019) Comparisons between reproducibility standard deviations (SDR) derived from proficiency tests and from collaborative trials: mycotoxins in food. Accred Qual Assur. https://doi.org/10.1007/s00769-019-01413-8

    Article  Google Scholar 

  21. Dajay LC, Portugal TR, Climaco JC, Parcon MRV, Udarbe MA, Placio REE, Adona PE (2018) Establishment of proficiency testing programs in the Philippines. Accred Qual Assur. https://doi.org/10.1007/s00769-018-1363-3

    Article  Google Scholar 

  22. Stefanelli P, Generali T, Girolimetti S, Barbini D (2018) Evaluation of the reproducibility standard deviation in the pesticide multi-residue methods on olive oil from past proficiency tests. Accred Qual Assur. https://doi.org/10.1007/s00769-018-1330-z

    Article  Google Scholar 

  23. Thiex N, Carlson M, Kieffer R, Kieffer A, Eisenberg D, Bararshkov N, Ramsey C (2019) Evaluation of the use of microtracers™ in a proficiency testing program. J AOAC Int. https://doi.org/10.5740/jaoacint.18-0354

    Article  PubMed  Google Scholar 

  24. Aryana N, Ryana N, Ramadhaningtyas DP, Styarini D, Arisriawan Y (2019) First Indonesian proficiency testing using reference value from isotope dilution mass spectrometry method for benzoic acid, methyl paraben, and n-butyl paraben in sweet soy sauce. Accred Qual Assur. https://doi.org/10.1007/s00769-019-01398-4

    Article  Google Scholar 

  25. Ferrini AM, Appicciafuoco B, Massaro MR, Galati F, Patriarca M (2019) Proficiency testing as an instrument to assess the analytical performance and the methods routinely implemented: the Italian experience for the screening of antibiotic residues in milk in the official control. Accred Qual Assur. https://doi.org/10.1007/s00769-018-1352-6

    Article  Google Scholar 

  26. Kim H, Hwang E, Park J, Heo SW, Yim YH, Lim Y, Lim MC, Lee JW, Lee KS (2019) Proficiency testing for total mercury in oyster with a metrologically traceable reference value from isotope dilution mass spectrometry: implications on laboratory practices using mercury analyzers. Accred Qual Assur. https://doi.org/10.1007/s00769-019-01379-7

    Article  Google Scholar 

  27. Ebarvia BS, Dacuya A, Cabanilla SR, Mamplata NR (2019) Provision of proficiency testing for histamine mass fraction in canned tuna to improve the capability of chemical laboratories in the Philippines. Accred Qual Assur. https://doi.org/10.1007/s00769-018-1347-3

    Article  Google Scholar 

  28. Generali T, Stefanelli P, Girolimetti S, Barbini DA (2019) Results of the 16th proficiency test on the determination of pesticide residues in olive oil. Accred Qual Assur. https://doi.org/10.1007/s00769-018-1329-5

    Article  Google Scholar 

  29. Middlebrook KA (2019) A proficiency testing scheme to evaluate the effectiveness of laboratory sample reduction of a soil sample. Accred Qual Assur. https://doi.org/10.1007/s00769-018-1357-1

    Article  Google Scholar 

  30. Ziegler E, Tirard A, Boubetra A, Bort M (2019) Acquisition of stability data for pesticides in water sample through proficiency tests. Accred Qual Assur. https://doi.org/10.1007/s00769-018-1339-3

    Article  Google Scholar 

  31. Coleman MD, Smith TOM, Robinson RA, Stoffels B, Wildanger D (2019) Combining UK and German emissions monitoring proficiency testing data based on stack simulator facilities to determine whether increasingly stringent EU emission limits are enforceable. Accred Qual Assur. https://doi.org/10.1007/s00769-018-1354-4

    Article  Google Scholar 

  32. Krismastuti FSH, Hamim N (2019) Designing a formulation of synthetic wastewater as proficiency testing sample: a feasibility study on a laboratory scale. Accred Qual Assur. https://doi.org/10.1007/s00769-019-01399-3

    Article  Google Scholar 

  33. Becker R, Sauer A, Bremeser W (2019) Fifteen years of proficiency testing of total petrol hydrocarbon determination in soil: a story of success. Accred Qual Assur. https://doi.org/10.1007/s00769-019-01383-x

    Article  Google Scholar 

  34. Leyva MJB, Batidas PJ, Muñiz VR, Ceballos MSG, Ponce VG, Aguilera MD, Grajeda CP, Navidad MMS, Flores MME, Ramírez COJA, Aguilar ZG, Huerta BG (2019) Measurement of organochlorine pesticides in drinking water: laboratory technical proficiency testing in Mexico. Accred Qual Assur. https://doi.org/10.1007/s00769-019-01403-w

    Article  Google Scholar 

  35. Olivares IRB, Souza GB, Nogueira ARA, Toledo GTK, Marcki DC (2018) Trends in devolpments of certified reference materials for chemical analysis—focus on food, water, soil and sedment matrices, trends in analytical chemistry. Trac Trends Anal Chem. https://doi.org/10.1016/j.trac.2017.12.013

    Article  Google Scholar 

  36. EPTIS (2020) About the database. https://eptis.org/about.htm. Accessed May 2020

  37. Baker M (2016) Is there a reproducibility crisis? Nature 533:452–454

    Article  CAS  Google Scholar 

  38. Lisinger TPJ, Pauwels J, Van Der Veen AMH, Schimmel H, Lamberty A (2001) Homogeneity and stability of reference materials. Accred Qual Assur. https://doi.org/10.1007/s007690000261

    Article  Google Scholar 

  39. ISO Guide 35:2017 Reference materials -- general and statistical principles for certification, 4th edition

  40. Thompson M, Ellison SLR, Wood R (2006) The international harmonized protocol for the proficiency testing of analytical chemistry laboratories (IUPAC technical report). Pure Appl Chem. https://doi.org/10.1351/pac200678010145

    Article  Google Scholar 

  41. RSC (2016) z-scores, and other scores in chemical proficiency testing—their meanings, and some common misconceptions. AMCTB. https://doi.org/10.1039/c6ay90078j

    Article  Google Scholar 

  42. Fearn T, Thompson MA (2001) A new test for ‘sufficient homogeneity.’ Analyst. https://doi.org/10.1039/b103812p

    Article  PubMed  Google Scholar 

  43. Dixon WJ (1960). Simplified estimation from censored normal samples. Ann Math Stat. https://www.jstor.org/stable/2237953

  44. Rivera C, Rodríguez R (2020) Horwitz equation as quality benchmark in ISO/IEC17025.TestingLaboratory. Available at: https://pdfs.semanticscholar.org/d6d6/a38d1a9e01e526ca4e2b5b8d804670e5414f.pdf?_ga=2.149818485. 2108515611.1564572314–1074601812.1564572314. Accessed 30 July 2020

  45. Horwitz W (1982) Evaluation of analytical methods used for regulations of food and drugs. Anal Chem. https://doi.org/10.1021/ac00238a765

    Article  Google Scholar 

Download references

Acknowledgements

We acknowledge financial support from the São Paulo State Research Foundation (FAPESP, 2020/01238-4, 2018/26145-9) and the National Council for Scientific and Technological Research (CNPq, grant 308178/2018-1).

Funding

Not applicable.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Igor Renato Bertoni Olivares.

Ethics declarations

Conflicts of interest

The authors declare that they have no conflict of interest.

Ethics approval

Not applicable.

Consent to participate

Not applicable.

Consent for publication

Not applicable.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Olivares, I.R.B., de Souza, G.B., de Araujo Nogueira, A.R. et al. Trends in the development of proficiency testing for chemical analysis: focus on food and environmental matrices. Accred Qual Assur 27, 55–83 (2022). https://doi.org/10.1007/s00769-021-01487-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00769-021-01487-3

Keywords

Navigation